2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
toluene-4-sulfonic acid; hydroquinone in Petroleum ether
参考文献
Saucy,G.; Marbet,R.
Helvetica Chimica Acta, 1967 , vol. 50, p. 1158 - 1167
反应条件
[Et3NH]+HSO4- T=95°C; Saucy-Marbet reaction; 24 h;
参考文献
Wang, Congmin; Zhao, Wenjia; Li, Haoran; Guo, Liping
Green Chemistry, 2009 , vol. 11, # 6 p. 843 - 847
反应条件
1: sodium 2: <180 View Scheme
参考文献
Samochwalow et al.
Zhurnal Obshchei Khimii, 1957 , vol. 27, p. 2501,2505; engl. Ausg. S. 2560, 2563
反应条件
1: 78 percent / propionic acid / 12 h / 130 °C 2: 95 percent / LiAlH4 / diethyl ether / 0.5 h 3: 78 percent / pyridine / 2 h / 0 °C 4: 95 percent / dimethylsulfoxide / 48 h / 20 °C 5: 81 percent / NaOH / ethanol; H2O / Heating View Scheme
参考文献
Jonasson; Horvath; Backvall
Journal of the American Chemical Society, 2000 , vol. 122, # 40 p. 9600 - 9609
反应条件
piperidine; copper (II) acetate monohydrate in dichloromethane T=25°C; 3 h; air;
参考文献
Balaraman, Kaluvu; Kesavan, Venkitasamy
Synthesis, 2010 , # 20 art. no. Z15010SS, p. 3461 - 3466
反应条件
1: 2-methyl-but-3-yn-2-ol With copper(l) iodide; P-olefin; triethylamine; bis(dibenzylideneacetone)-palladium(0) in N,N-dimethyl-formamide 0.0833333 h; Inert atmosphere; 2: 1-bromo-2-phenylacetylene in N,N-dimethyl-formamide T=20 - 25°C; 9 h; Inert atmosphere;
参考文献
Shi, Wei; Luo, Yingdong; Luo, Xiancai; Chao, Lei; Zhang, Heng; Wang, Jian; Lei, Aiwen
Journal of the American Chemical Society, 2008 , vol. 130, # 44 p. 14713 - 14720
反应条件
copper acetylacetonate; iron (III) acetylacetonate; potassium carbonate in N,N-dimethyl-formamide T=50°C; 12 h;
参考文献
Zhang, Songlin; Liu, Xiaoyan; Wang, Tongqiang
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1463 - 1466
反应条件
hydroxylamine hydrochloride; N-butylamine; copper(l) chloride in methanol; water T=20°C;
参考文献
Jiang, May Xiao-Wu; Rawat, Manish; Wulff, William D.
Journal of the American Chemical Society, 2004 , vol. 126, # 19 p. 5970 - 5971
反应条件
copper(l) iodide; triethylamine in N,N-dimethyl-formamide T=20°C; 16 h; Inert atmosphere;
参考文献
Li, Hongling; Wang, Lailai; Yang, Min; Qi, Yanxing
Catalysis Communications, 2012 , vol. 17, p. 179 - 183
反应条件
copper(l) iodide; N,N,N',N,-tetramethylethylenediamine; triethylamine in acetone T=20°C; 20 h;
参考文献
Zhang, Songlin; Liu, Xiaoyan; Wang, Tongqiang
Advanced Synthesis and Catalysis, 2011 , vol. 353, # 9 p. 1463 - 1466
