2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
sodium hydroxide; 2,2'-azo-bisisobutyronitrile in dichloromethane
T=10°C; Product distribution; Further Variations:ReagentsSolventsTemperatures;
参考文献
Calleja-Rubio; Crette; Blancou
Synthesis, 2003 , # 3 p. 361 - 364
反应条件
potassium hydroxide in neat (no solvent)
T=115°C; 0.5 h; Yield given. Yields of byproduct given;
参考文献
Ruel, Odile; Guittet, Eric; Julia, Sylvestre
Tetrahedron Letters, 1983 , vol. 24, # 1 p. 61 - 64
反应条件
bis(acetylacetonate)nickel(II)
T=40°C; 0.666667 h;
参考文献
Ananikov; Zalesskiy; Orlov; Beletskaya
Russian Chemical Bulletin, 2006 , vol. 55, # 11 p. 2109 - 2113
反应条件
potassium hydroxide
1)40-50 deg C,3h; 2)100-105 deg C, 6h;
参考文献
Dzhafarov, A. A.; Aslanov, I. A.; Trofimov, B. A.; Ibadzade, A. K.; Ibragimov, N. Yu.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 643 - 646
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 4 p. 739 - 743
反应条件
cyclohexyl-mercaptan; palladium diacetate
T=100°C; 4 h; Inert atmosphere;
参考文献
Ananikov, Valentine P.; Orlov, Nikolay V.; Zalesskiy, Sergey S.; Beletskaya, Irina P.; Khrustalev, Victor N.; Morokuma, Keiji; Musaev, Djamaladdin G.
Journal of the American Chemical Society, 2012 , vol. 134, # 15 p. 6637 - 6649
反应条件
palladium diacetate
T=120°C; 8 h; Inert atmosphere;
参考文献
Ananikov, Valentine P.; Orlov, Nikolay V.; Zalesskiy, Sergey S.; Beletskaya, Irina P.; Khrustalev, Victor N.; Morokuma, Keiji; Musaev, Djamaladdin G.
Journal of the American Chemical Society, 2012 , vol. 134, # 15 p. 6637 - 6649
反应条件
palladium diacetate
Inert atmosphere;
参考文献
Ananikov, Valentine P.; Orlov, Nikolay V.; Zalesskiy, Sergey S.; Beletskaya, Irina P.; Khrustalev, Victor N.; Morokuma, Keiji; Musaev, Djamaladdin G.
Journal of the American Chemical Society, 2012 , vol. 134, # 15 p. 6637 - 6649
反应条件
potassium hydroxide
1)40-50 deg C,3h; 2)100-105 deg C, 6h;
参考文献
Dzhafarov, A. A.; Aslanov, I. A.; Trofimov, B. A.; Ibadzade, A. K.; Ibragimov, N. Yu.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 643 - 646
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 4 p. 739 - 743
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide in triethylamine
T=40°C; 3 h;
参考文献
Mongin, Olivier; Gossauer, Albert
Tetrahedron, 1997 , vol. 53, # 20 p. 6835 - 6846
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine
T=80 - 85°C; Sonogashira coupling; 24 h; Inert atmosphere;
参考文献
Guan, Xiao-Lin; Zhang, Lan-Ying; Zhang, Zhen-Lin; Shen, Zhihao; Chen, Xiao-Fang; Fan, Xing-He; Zhou, Qi-Feng
Tetrahedron, 2009 , vol. 65, # 18 p. 3728 - 3732
