2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
反应条件
hydrogen in water
T=45°C; P=760 Torr; 10 h; <Me2C(OH)CCH>/<Co> : 2; Yield given. Yields of byproduct given;
参考文献
Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918
反应条件
Ni(phmep)2; alpha,alpha'-bis(diphenylphosphino)-o-xylene in benzene
T=120°C; 18 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Jackson, W. Roy; Lovel, Craig G.; Perlmutter, Patrick; Smallridge, Andrew J.
Australian Journal of Chemistry, 1988 , vol. 41, # 7 p. 1099 - 1106
反应条件
pentacyanocobaltate(II)(3-); hydrogen in water
P=760 Torr; 10 h; different reagent ratio; Product distributionMechanism;
参考文献
Funabiki, Takuzo; Yamazaki, Yasuyuki; Sato, Yoshihiro; Yoshida, Satohiro
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 12 p. 1915 - 1918
参考文献
Cutting, Ian; Parsons, Philip J.
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210
反应条件
1: 56 percent / nBuLi
2: 75 percent
View Scheme
参考文献
Cutting, Ian; Parsons, Philip J.
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210
反应条件
1: 56 percent / nBuLi
2: 82 percent / tetrahydrofuran
View Scheme
参考文献
Cutting, Ian; Parsons, Philip J.
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210
反应条件
1: 56 percent / nBuLi
2: 75 percent
3: 53 percent / HgCl2 / acetonitrile; H2O
View Scheme
参考文献
Cutting, Ian; Parsons, Philip J.
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210
反应条件
1: 56 percent / nBuLi
2: 82 percent / tetrahydrofuran
3: 48 percent / HgCl2 / acetonitrile; H2O
View Scheme
参考文献
Cutting, Ian; Parsons, Philip J.
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210
反应条件
1: 2.) PTSA
2: 1.) BuLi
3: 1.) LiAlH4, 2.) aq. NaOH
4: 1.) MeLi / 1.) THF, -45 deg C, 2 h, 2.) THF, from -45 deg C to RT, 2 h
View Scheme
参考文献
Wright, Marcus W.; Smalley Jr., Terrence L.; Welker, Mark E.; Rheingold, Arnold L.
Journal of the American Chemical Society, 1994 , vol. 116, # 15 p. 6777 - 6791
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; diethylamine
T=0 - 20°C; 12 h;
参考文献
Geary, Laina M.; Leung, Joyce C.; Krische, Michael J.
Chemistry - A European Journal, 2012 , vol. 18, # 52 p. 16823 - 16827
