1-硫代-b-甲基葡萄糖甙-4-甲基苯酯合成路线 （共 26 条）
反应条件
1: 64 percent / NaH / dimethylformamide / 1.) 30 min, 2.) 80 deg C, 3.5 h 2: acetonitrile / electrochemical synthesis: one compartment, three-electrode, air-tight cell, vitrous carbon anode and Pt catode, 0.2 M LiClO4 as supporting electrolyte, constant potential 1.45 V (vs standard calomel reference electrode) View Scheme
参考文献
Balovoine, Gilbert; Berteina, Sabine; Gref, Aurore; Fischer, Jean-Claude; Lubineau, Andre
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 8 p. 1217 - 1236
反应条件
1.) electrochemical synthesis: one compartment, three-electrode, air-tight cell, Pt anode and catode, 0.2 M LiClO4 in MeCN as supporting electrolyte, constant potential 1.38 V (vs standard calomel reference electrode); Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Balovoine, Gilbert; Berteina, Sabine; Gref, Aurore; Fischer, Jean-Claude; Lubineau, Andre
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 8 p. 1217 - 1236
反应条件
in acetonitrile T=30°C; 8 h; anodic oxidation (Pt electrode, LiClO4 as electrolyte); Yield given;
参考文献
Balavoine, Gilbert; Gref, Aurore; Fischer, Jean-Claude; Lubineau, Andre
Tetrahedron Letters, 1990 , vol. 31, # 40 p. 5761 - 5764
反应条件
(6AR,6DR)-6A,6D-di-C-cyano-β-cyclodextrin in phosphate buffer T=59°C; pH=8.0; Kinetics;
参考文献
Ortega-Caballero, Fernando; Bjerre, Jeannette; Laustsen, Line Skall; Bols, Mikael
Journal of Organic Chemistry, 2005 , vol. 70, # 18 p. 7217 - 7226
反应条件
lithium perchlorate 1 h; Heating;
参考文献
Lu, Kuo-Cheng; Hsieh, Shu-Yi; Patkar, Laxmikant N.; Chen, Chien-Tien; Lin, Chun-Cheng
Tetrahedron, 2004 , vol. 60, # 40 p. 8967 - 8973
反应条件
1: 64 percent / NaH / dimethylformamide / 1.) 30 min, 2.) 80 deg C, 3.5 h 2: acetonitrile / electrochemical synthesis: one compartment, three-electrode, air-tight cell, vitrous carbon anode and Pt catode, 0.2 M LiClO4 as supporting electrolyte, constant potential 1.45 V (vs standard calomel reference electrode) View Scheme
参考文献
Balovoine, Gilbert; Berteina, Sabine; Gref, Aurore; Fischer, Jean-Claude; Lubineau, Andre
Journal of Carbohydrate Chemistry, 1995 , vol. 14, # 8 p. 1217 - 1236
反应条件
toluene-4-sulfonic acid in N,N-dimethyl-formamide T=50°C; 0.0223333 h;
参考文献
Vargas-Berenguel, Antonio; Meldal, Morten; Paulsen, Hans; Jensen, Knud J.; Bock, Klaus
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 22 p. 3287 - 3294
反应条件
toluene-4-sulfonic acid in acetonitrile T=20°C; 5 h;
参考文献
Dhenin, Sandrine G.Y.; Moreau, Vincent; Morel, Nathalie; Nevers, Marie-Claire; Volland, Herve; Creminon, Christophe; Djedaini-Pilard, Florence
Carbohydrate Research, 2008 , vol. 343, # 12 p. 2101 - 2110
反应条件
sodium hydrogen sulphate; silica gel in acetonitrile
T=20°C; 2 h;
参考文献
Niu, Youhong; Wang, Ning; Cao, Xiaoping; Ye, Xin-Shan
Synlett, 2007 , # 13 p. 2116 - 2120
反应条件
VO(OTf)2 in acetonitrile
T=20°C; 8 h;
参考文献
Chen, Chien-Tien; Weng, Shiue-Shien; Kao, Jun-Qi; Lin, Chun-Cheng; Jan, Mi-Dan
Organic Letters, 2005 , vol. 7, # 15 p. 3343 - 3346
