1: 67 percent / Na2S / aq. ethanol / 4 h / 20 °C 2: 65 percent / Oxone / CH2Cl2 / 50 °C 3: 65 percent / KOH-Al2O3; CBr2F2 / CH2Cl2 View Scheme

Multi-step reaction with 3 steps 1: 1.) n-BuLi, 2.) HMPA / 1.) THF, hexane, -78 deg C, 10 min, 2.) THF, hexane, a) from -78 deg C to RT, 2 h, b) RT, 16 h2: pyridinium p-toluenesulfonate / methanol / 18 h3: 92 percent / CBr4, n-Bu3P / diethyl ether / 0.25 h / 0 °C  

With  sodium sulfide in  ethanol T=20°C; 4 h;   

Multi-step reaction with 4 steps 1: 31 percent / Na2S*9H2O / ethanol; H2O / 25 °C2: 68 percent / m-chloroperbenzoic acid / CH2Cl2 / 0.5 h / -30 °C3: pyridine, SO2Cl2 / CH2Cl2 / 0.67 h / -78 °C4: m-chloroperbenzoic acid / CH2Cl2 / 16 h / Ambient temperature