(氯二氟甲基)三甲基硅烷合成路线 （共 26 条）
反应条件
tetrabutyl-ammonium chloride; AgCl in benzonitrile T=20°C; 6 h; TimeTemperatureReagent/catalystSolvent;
参考文献
Wang, Fei; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo
Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 344 - 351
反应条件
phosphorous acid trisdiethylamide in various solvent(s) T=-78 - 20°C;
参考文献
Broicher, Volker; Geffken, Detlef
Journal of Organometallic Chemistry, 1990 , vol. 381, # 3 p. 315 - 320
反应条件
1-methyl-pyrrolidin-2-one; aluminium Ambient temperature;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
1-methyl-pyrrolidin-2-one; aluminium 1.) room temperature, overnight; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
1-methyl-pyrrolidin-2-one; aluminium Ambient temperaturevarious reactant ratio, other temperature, ultrasound promotion; MechanismProduct distribution;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; chloro-trimethyl-silane; tetrabutyl ammonium fluoride; tetrabutylammomium bromide 1.) THF, electrolysis, Al anode, Ni cathode, 2.) THF; Multistep reaction. Yields of byproduct given;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; tetrabutyl ammonium fluoride; tetrabutylammomium bromide 1.) THF, electrolysis, Al anode, Ni cathode; other reagents: tris(3,6-dioxaheptyl)amine, magnesium, tetrabutylammonium hexafluorophosphate, 2.) THF; Yield given. Multistep reaction. Further byproducts given;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
triphenylphosphine in tetrahydrofuran T=80°C; Wittig Olefination; 10 h; Sealed tube;
参考文献
Wang, Fei; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo
Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 344 - 351
反应条件
tetrabutyl ammonium fluoride; phenylacetylene in tetrahydrofuran T=110°C; 4 h;
参考文献
Wang, Fei; Zhang, Wei; Zhu, Jieming; Li, Huaifeng; Huang, Kuo-Wei; Hu, Jinbo
Chemical Communications, 2011 , vol. 47, # 8 p. 2411 - 2413
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; tetrabutylammomium bromide in tetrahydrofuran electrolysis, Al anode, Ni cathode, other reagents: tris(3,6-dioxaheptyl)amine, tetrabutylammonium hexafluorophosphate, magnesium, various current density, various reactant ratios; MechanismProduct distribution;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
