溴二氟(三甲基硅基)甲烷合成路线 （共 24 条）
反应条件
potassium hydroxide in dichloromethane; water T=0°C; 0.5 h;
参考文献
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5
反应条件
tetrabutyl-ammonium chloride; AgCl in benzonitrile T=20°C; 6 h; TimeTemperatureReagent/catalystSolvent;
参考文献
Wang, Fei; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo
Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 344 - 351
反应条件
potassium hydroxide in dichloromethane; water T=0°C; 0.5 h;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., , vol. 125, # 47 p. 12616 - 12620,5
反应条件
sulfuric acid; dihydrogen peroxide; sodium bromide in water
T=40°C; 1 h; IrradiationInert atmosphere;
参考文献
Kosobokov, Mikhail D.; Dilman, Alexander D.; Levin, Vitalij V.; Struchkova, Marina I.
Journal of Organic Chemistry, 2012 , vol. 77, # 13 p. 5850 - 5855
反应条件
1-methyl-pyrrolidin-2-one; aluminium
Ambient temperature;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
boron tribromide in dichloromethane
T=15°C; 0.0333333 h; Inert atmosphere;
参考文献
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5
反应条件
1-methyl-pyrrolidin-2-one; aluminium
Ambient temperature;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
1-methyl-pyrrolidin-2-one; aluminium
Ambient temperaturevarious reactant ratio, other temperature, ultrasound promotion; MechanismProduct distribution;
参考文献
Yudin, Andrei K.; Prakash, G. K. Surya; Deffieux, Denis; Bradley, Michael; Bau, Robert; Olah, George A.
Journal of the American Chemical Society, 1997 , vol. 119, # 7 p. 1572 - 1581
反应条件
tetrabutylammomium bromide in toluene
T=20 - 110°C; 2 h; Inert atmosphere;
参考文献
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5
反应条件
potassium hydroxide in dichloromethane; water
T=0°C; 0.5 h;
参考文献
Li, Lingchun; Wang, Fei; Ni, Chuanfa; Hu, Jinbo
Angewandte Chemie - International Edition, 2013 , vol. 52, # 47 p. 12390 - 12394
Angew. Chem., 2013 , vol. 125, # 47 p. 12616 - 12620,5
