H2 in benzene H2 is bubbled through a soln. of Rh complex for 5 min.; identification of organic compounds in soln., evapn. of volatile substances yields mainly metallic Rh as residue;
in dichloromethane instant reaction; no sepn. of metal-contg. products (similar soly.);
参考文献
Zeijden, Adolphus A. H. van der; Koten, Gerard van; Nordemann, Richard A.; Kojic-Prodic, Biserka; Spek, Anthony L.
Organometallics, 1988 , vol. 7, p. 1957 - 1966
H2 in benzene H2 is bubbled through a soln. of Rh complex for 5 min.; identification of organic compounds in soln., evapn. of volatile substances yields mainly metallic Rh as residue;
参考文献
Zeijden, Adolphus A. H. van der; Koten, Gerard van; Nordemann, Richard A.; Kojic-Prodic, Biserka; Spek, Anthony L.
Organometallics, 1988 , vol. 7, p. 1957 - 1966
HgCl2 in dichloromethane instant reaction; no sepn. of metal-contg. products (similar soly.);
参考文献
Zeijden, Adolphus A. H. van der; Koten, Gerard van; Nordemann, Richard A.; Kojic-Prodic, Biserka; Spek, Anthony L.
Organometallics, 1988 , vol. 7, p. 1957 - 1966
HCl in benzene HCl is bubbled for 1 min through a soln. of Rh complex.; addn. of water, sepn. of layers; evapn. of benzene layer yields (RhCl(COD))2, ammonium salt of aryl compound is obtained from water layer.;
in dichloromethane instant reaction; no sepn. of metal-contg. products (similar soly.);
参考文献
Zeijden, Adolphus A. H. van der; Koten, Gerard van; Nordemann, Richard A.; Kojic-Prodic, Biserka; Spek, Anthony L.
Organometallics, 1988 , vol. 7, p. 1957 - 1966
