反应条件
1: phenyl-magnesium bromide With ZnCl2*TMEDA in tetrahydrofuran
T=0°C; Inert atmosphere;
2: N-(1-(4-iodophenyl)ethylidene)-4-methoxybenzenamine With iron (III) acetylacetonate; 1,2-dichloro-2-methylpropane; 4,4'-di-tert-butyl-2,2'-dipyridyl in tetrahydrofuran
T=0°C; 3 h; Inert atmosphere;
3: With hydrogenchloride; water in tetrahydrofuran
T=20°C; 3 h; chemoselective reaction;
参考文献
Yoshikai, Naohiko; Matsumoto, Arimasa; Norinder, Jakob; Nakamura, Eiichi
Angewandte Chemie, International Edition, 2009 , vol. 48, # 16 p. 2925 - 2928