1-苯基-2-(4-苯基苯基)苯合成路线 （共 28 条）
反应条件
1: 96 percent / iron (activated) / benzene / Heating
2: 1.) NaNO2, conc. H2SO4; 2.) KI / 1.) water, 0-5 deg C, 2 h; 2.) water, 0-5 deg C
3: 313 mg / copper powder / 1.) 265-270 deg C, 2 h; 2.) 270-275 deg C, 0.5 h
View Scheme
参考文献
Ozasa; Fujioka; Tsukada; Ibuki
Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 2 p. 344 - 355
反应条件
1: 95 percent / iron (activated) / benzene / Heating
2: 1.) NaNO2, conc. H2SO4; 2.) KI / 1.) water, 0-5 deg C, 2 h; 2.) water, 0-5 deg C
3: 154 mg / copper powder / 1.) 265-270 deg C, 2 h; 2.) 270-275 deg C, 0.5 h
View Scheme
参考文献
Ozasa; Fujioka; Tsukada; Ibuki
Chemical and Pharmaceutical Bulletin, 1981 , vol. 29, # 2 p. 344 - 355
反应条件
1: Fe / benzene
2: (i) NaNO2, H2SO4, (ii) aq. KI
3: Cu / 265 - 270 °C
View Scheme
参考文献
Ibuki,E. et al.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 1868 - 1874
反应条件
copper
T=265 - 270°C;
参考文献
Ibuki,E. et al.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 1868 - 1874
参考文献
Dale
Acta Chemica Scandinavica (1947-1973), 1957 , vol. 11, p. 640,641
反应条件
2: <1,4>benzoquinone, Al(OiPr)3
4: Pd-C / 290 °C
View Scheme
参考文献
Woods,G.F.; Scotti,F.
Journal of Organic Chemistry, 1961 , vol. 26, p. 312 - 318
反应条件
1: (i) Mg, (ii) /BRN= 774100/
3: Pd-C / 290 °C
View Scheme
参考文献
Woods,G.F.; Scotti,F.
Journal of Organic Chemistry, 1961 , vol. 26, p. 312 - 318
反应条件
1: (i) NaNO2, H2SO4, (ii) aq. KI
2: Cu / 265 - 270 °C
View Scheme
参考文献
Ibuki,E. et al.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 1868 - 1874
反应条件
1: (i) NaNO2, H2SO4, (ii) aq. KI
2: Cu / 265 - 270 °C
View Scheme
参考文献
Ibuki,E. et al.
Bulletin of the Chemical Society of Japan, 1975 , vol. 48, p. 1868 - 1874
反应条件
carbon dioxide; 1-iso-propyl-4-methylbenzene
参考文献
Copeland,P.G. et al.
Journal of the Chemical Society, 1960 , p. 4522 - 4524
