methanol in methanol under N2, soln. of Mn(CO)5(CpFeC5H4) in MeOH stirred at room temp. for 67 h; evapd., extd. with pentane, evapd., taken up in CH2Cl2, sepd. by columnchromy. (Kieselgel, CH2Cl2);

propene; carbon monoxide; hydrogen in N,N-dimethyl-formamide High Pressure; soln. of Mn(CO)5(CpFeC5H4) in DMF pressurised in autoclave successivelywith 8 bar of propene, 15 bar of CO, and 15 bar of H2, stirred at 100°C for 20 h; evapd. in vac., extd. with CH2Cl2, sepd. by preparative thin layer chromy. (CH2Cl2);

in acetonitrile under N2, soln. of Mn(CO)5(CpFeC5H4) in MeCN stirred for 63 h at room temp.; filtered through Na2SO4, evapd., extd. with pentane, concd., chromd. (Kieselgel; pentane, CH2Cl2, Et2O);

propene; carbon monoxide; hydrogen in N,N-dimethyl-formamide High Pressure; soln. of Mn(CO)5(CpFeC5H4) in DMF pressurised in autoclave successivelywith 8 bar of propene, 15 bar of CO, and 15 bar of H2, stirred at 100°C for 20 h; evapd. in vac., extd. with CH2Cl2, sepd. by preparative thin layer chromy. (CH2Cl2);

triphenylphosphine in toluene under N2, Mn(CO)5(CpFeC5H4) and PPh3 dissolved in toluene, kept at 100°C for 4 h; evapd., extd. with pentane, concd., sepd. by column chromy. (Kieselgel;pentane, CH2Cl2), crystd. from pentane at -78°C;

propene; carbon monoxide; hydrogen in N,N-dimethyl-formamide High Pressure; soln. of Mn(CO)5(CpFeC5H4) in DMF pressurised in autoclave successivelywith 8 bar of propene, 15 bar of CO, and 15 bar of H2, stirred at 100°C for 20 h; evapd. in vac., extd. with CH2Cl2, sepd. by preparative thin layer chromy. (CH2Cl2);

in acetonitrile under N2, soln. of Mn(CO)5(CpFeC5H4) in MeCN stirred for 63 h at room temp.; filtered through Na2SO4, evapd., extd. with pentane, concd., chromd. (Kieselgel; pentane, CH2Cl2, Et2O);

in acetonitrile at 60°C;

in tetrahydrofuran under N2, to soln. of Mn(CO)5(CpFeC5H4) in THF added t-BuNC, heated at 60°C for 1.5 h; evapd., sepd. by column chromy. (Kieselgel; pentane, CH2Cl2, CH2Cl2/Et2O), crystd. from pentane at -78°C;