10,15-二氢-2,3,7,8,12,13-六甲氧基-5H-三苯并[a,d,g]环壬烯合成路线 （共 28 条）
反应条件
1: PBr3 / CH2Cl2 / 1.) 0 deg C, 1.5 h, 2.) r.t., 1 h
2: ZnCl2, NaBH3CN / tetrahydrofuran / 5 h / Ambient temperature
View Scheme
参考文献
Hara, Hiroshi; Watanabe, Shin-ichi; Yamada, Makoto; Hoshino, Osamu
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1996 , # 7 p. 741 - 746
反应条件
1: LiAlH4
2: HClO4 / CHCl3
View Scheme
参考文献
Umezawa,B. et al.
Journal of the Chemical Society [Section] C: Organic, 1970 , vol. <C>, p. 465 - 467
反应条件
lithium isopropyl amide in tetrahydrofuran
2 h;
参考文献
Carmody, Maurice P.; Sainsbury, Malcolm; Newton, Roger F.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 2013 - 2020
反应条件
sulfuric acid; acetic acid
T=90°C; 0.25 h;
参考文献
Barbour, Leonard J.; Steed, Jonathan W.; Atwood, Jerry L.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1995 , # 4 p. 857 - 860
反应条件
hydrogenchloride
T=0°C;
参考文献
Bide; Wilkinson
Journal of the Society of Chemical Industry, London, 1945 , vol. 64, p. 84
参考文献
Carre; Libermann
Bulletin de la Societe Chimique de France, 1935 , vol. <5> 2, p. 291,294
参考文献
Umezawa,B. et al.
Chemical and Pharmaceutical Bulletin, 1969 , vol. 17, p. 2240 - 2244
反应条件
1: aqueous H2SO4
2: aqueous H2SO4
View Scheme
参考文献
Oliverio; Casinovi
Annali di Chimica (Rome, Italy), 1952 , vol. 42, p. 168,175
反应条件
1: AlCl3
2: aqueous H2SO4
View Scheme
参考文献
Oliverio; Casinovi
Annali di Chimica (Rome, Italy), 1952 , vol. 42, p. 168,175
参考文献
Oliverio; Casinovi
Annali di Chimica (Rome, Italy), 1952 , vol. 42, p. 168,175
