methylmagnesium bromide in diethyl ether react. with an excess of HGeCl3 at 80°C; then react. with CH3MgBr in ether; gas-liquid chromy.; (1)H-, (13)C-NMR;
参考文献
Kolesnikov, S. P.; Povarov, S. L.; Nefedov, O. M.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, p. 1320 - 1321
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , p. 1453 - 1453
Mironov, V. F.; Kravchenko, A. L.
Doklady Akademii Nauk SSSR, 1964 , vol. 154/159, p. 949 - 952
Doklady Akademii Nauk SSSR, 1964 , vol. 158, p. 656 - 659
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Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.16.1.4.5, page 159 - 161
in neat (no solvent) slow heating; beginning of the decompn. at 140 °C; formation of GeCl2 and HCl by vigorous decompn. at 175 °C; further heating generates Ge and GeCl4;;
参考文献
Brewer, F. M.; Dennis, L. M.
Journal of Physical Chemistry, 1927 , vol. 31, p. 1537 - 1537
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Gmelin Handbook: Ge: MVol., 15, page 44 - 46
water in tetrahydrofuran treatment od reaction mixt. in THF with excess EtMgBr, hydrolysis; extn. (ether), drying over Na2SO4; identification of individual compds.;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 82, # 1-4 p. 181 - 194
