9-苯甲基-3,6-二溴咔唑合成路线 （共 9 条）
反应条件
1: 3,6-dibromo-9H-carbazole With sodium hydride in N,N-dimethyl-formamide 1 h; 2: benzyl bromide in N,N-dimethyl-formamide 6 h; Further stages.;
参考文献
Xing, Jin-Feng; Chen, Wei-Qiang; Gu, Jie; Dong, Xian-Zi; Takeyasu, Nobuyuki; Tanaka, Takuo; Duan, Xuan-Ming; Kawata, Satoshi
Journal of Materials Chemistry, 2007 , vol. 17, # 14 p. 1433 - 1438
反应条件
1: 3,6-dibromo-9H-carbazole With sodium hydride in tetrahydrofuran T=20°C; 0.5 h; 2: benzyl bromide in tetrahydrofuran 20 h;
参考文献
Semiconductor Energy Laboratory Co., Ltd.
Patent: US2005/31899 A1, 2005 ;
Location in patent: Page/Page column 18-19 ;
反应条件
bromine in acetic acid T=20°C; 2 h;
参考文献
Hensel, Thomas; Trpcevski, Denis; Lind, Christopher; Grosjean, Remi; Hammershoj, Peter; Nielsen, Christian B.; Brock-Nannestad, Theis; Nielsen, Bjarne E.; Schau-Magnussen, Magnus; Minaev, Boris; Baryshnikov, Gleb V.; Pittelkow, Michael
Chemistry - A European Journal, 2013 , vol. 19, # 50 p. 17097 - 17102
反应条件
potassium carbonate in N,N-dimethyl-formamide T=100°C; 12 h;
参考文献
Wright, Michael E.; Jin, Myung-Jong
Journal of Organic Chemistry, 1989 , vol. 54, # 4 p. 965 - 968
反应条件
Tsunoda reagent in toluene T=110°C; 15 h;
参考文献
Bombrun, Agnes; Casi, Giulio
Tetrahedron Letters, 2002 , vol. 43, # 12 p. 2187 - 2190
反应条件
1: sodium amide; toluene / Erhitzen des Reaktionsgemisches mit Benzylchlorid 2: acetic acid; bromine View Scheme
参考文献
Zhang, Caihong; Li, Feng; Wang, Yue; Feng, Liheng
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2013 , vol. 113, p. 159 - 163
反应条件
1.1: potassium hydroxide / tetrahydrofuran / 2 h / |Reflux 1.2: 24 h / |Reflux 2.1: bromine; acetic acid / 24 h / 20 °C View Scheme
参考文献
Zhang, Caihong; Li, Feng; Wang, Yue; Feng, Liheng
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2013 , vol. 113, p. 159 - 163
反应条件
in dimethyl sulfoxide T=25°C; Rate constant;
参考文献
Bordwell, Frederick G.; Hughes, David L.
Journal of the American Chemical Society, 1984 , vol. 106, # 11 p. 3234 - 3240
反应条件
N-bromosuccinmide in dichloromethane T=20°C; 0.833333 h; Product distribution; Further Variations:ReagentsSolvents;
参考文献
Ponce, Maria B.; Cabrerizo, Franco M.; Bonesi, Sergio M.; Erra-Balsells, Rosa
Helvetica Chimica Acta, 2006 , vol. 89, # 6 p. 1123 - 1139
