4-三甲基甲硅烷基苯硼酸频那醇酯合成路线 （共 4 条）
反应条件
in acetone T=20°C; Inert atmosphere;
参考文献
Tsoi, Yuk-Tai; Zhou, Zhongyuan; Yu, Wing-Yiu
Organic Letters, 2011 , vol. 13, # 19 p. 5370 - 5373
反应条件
1: 4-(trimethylsilyl)bromobenzene in N,N-dimethyl-formamide 0.5 h; Inert atmosphere; 2: 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate in N,N-dimethyl-formamide T=80°C; 18 h; Inert atmosphere;
参考文献
Schubert, Christina; Wielopolski, Mateusz; Mewes, Lars-Hendrik; De Miguel Rojas, Gustavo; Van Der Pol, Cornelia; Moss, Kathryn C.; Bryce, Martin R.; Moser, Jacques E.; Clark, Timothy; Guldi, Dirk M.
Chemistry - A European Journal, 2013 , vol. 19, # 23 p. 7575 - 7586
反应条件
1: 4-(trimethylsilyl)bromobenzene With n-butyllithium in tetrahydrofuran; hexane T=-80°C; 0.25 h; Inert atmosphere; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=20°C;
参考文献
Sakamoto, Youichi; Suzuki, Toshiyasu
Journal of the American Chemical Society, 2013 , vol. 135, # 38 p. 14074 - 14077
反应条件
methoxylamine hydrochloride; n-butyllithium in tetrahydrofuran; hexane T=-78 - 60°C; 24 h; Inert atmosphereCooling with acetone-dry ice; stereospecific reaction;
参考文献
Mlynarski, Scott N.; Karns, Alexander S.; Morken, James P.
Journal of the American Chemical Society, 2012 , vol. 134, # 40 p. 16449 - 16451,3
