反式-5-叔丁基二甲基硅烷基氧基-2-戊烯醛合成路线 （共 7 条）
反应条件
Grubb's 2nd generation catalyst in dichloromethane T=40°C; 3 h; Inert atmosphere; optical yield given as percent dediastereoselective reaction;
参考文献
Sirasani, Gopal; Paul, Tapas; Andrade, Rodrigo B.
Tetrahedron, 2011 , vol. 67, # 12 p. 2197 - 2205
反应条件
[2,2']bipyridinyl; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; 5,6,9,10-tetrahydro-4H,8H-pyrido[3,2,1-ij][1,6]naphthyridine; oxygen; copper(I) bromide in acetonitrile T=20°C; 25 h; Schlenk technique;
参考文献
Koenning, Daniel; Olbrisch, Tobias; Sypaseuth, Fanni D.; Tzschucke, C. Christoph; Christmann, Mathias
Chemical Communications, 2014 , vol. 50, # 39 p. 5014 - 5016
反应条件
Grubb's 2nd generation catalyst in dichloromethane T=40°C; 3 h;
参考文献
Paul, Tapas; Sirasani, Gopal; Andrade, Rodrigo B.
Tetrahedron Letters, 2008 , vol. 49, # 21 p. 3363 - 3367
反应条件
in benzene 5 h; Heating;
参考文献
Cardani, Silvia; De Toma, Carlo; Gennari, Cesare; Scolastico, Carlo
Tetrahedron, 1992 , vol. 48, # 27 p. 5557 - 5564
反应条件
1: 1) ClCO-COCl, DMSO, 2) NEt3 / 1) CH2Cl2, -70 deg C, 2) -30 to 0 deg C 2: 80 percent / benzene / 5 h / Heating View Scheme
参考文献
Cardani, Silvia; De Toma, Carlo; Gennari, Cesare; Scolastico, Carlo
Tetrahedron, 1992 , vol. 48, # 27 p. 5557 - 5564
反应条件
1: 83 percent / NaH / tetrahydrofuran 2: 1) ClCO-COCl, DMSO, 2) NEt3 / 1) CH2Cl2, -70 deg C, 2) -30 to 0 deg C 3: 80 percent / benzene / 5 h / Heating View Scheme
参考文献
Cardani, Silvia; De Toma, Carlo; Gennari, Cesare; Scolastico, Carlo
Tetrahedron, 1992 , vol. 48, # 27 p. 5557 - 5564
反应条件
diisobutylaluminium hydride in dimethyl sulfoxide
T=-78°C; 2 h;
参考文献
Sirasani, Gopal; Paul, Tapas; Andrade, Rodrigo B.
Tetrahedron, 2011 , vol. 67, # 12 p. 2197 - 2205
