4-[3,5-二(4-甲酰基苯基)苯基]苯甲醛合成路线 （共 10 条）
反应条件
sodium carbonate; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; toluene T=80°C; Suzuki-Miyaura cross-coupling; 16 h;
参考文献
Synthesis, , # 23 p. 3653 - 3658
反应条件
1: TBB With tert.-butyl lithium in tetrahydrofuran; pentane T=-78°C; 1 h; Inert atmosphere; 2: N,N-dimethyl-formamide in tetrahydrofuran; pentane 2 h; Inert atmosphere;
参考文献
European Journal of Organic Chemistry, , # 12 p. 2422 - 2427
反应条件
tetra(n-butyl)ammonium dichromate(VI) in chloroform 6 h; Heating;
参考文献
Tetrahedron, , vol. 62, # 51 p. 12041 - 12050
反应条件
n-butyllithium in hexane; benzene 1.) 55-60 deg C, 6-7 h; 2.) to RT;
参考文献
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), , p. 1251 - 1258
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in tetrahydrofuran; water 48 h; RefluxInert atmosphere;
参考文献
Journal of Materials Chemistry, , vol. 21, # 14 p. 5451 - 5456
反应条件
1.1: K2S2O7; H2SO4 / 180 °C 2.1: butyllithium / benzene / 60 °C 2.2: benzene / 0 - 20 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 46, # 46 p. 7871 - 7875
反应条件
1.1: palladium(II) dichloride bis[bis(diphenylphosphine)ferrocene]; potassium acetate / dimethyl sulfoxide / 0.17 h / Inert atmosphere 1.2: 24 h / 80 °C / Inert atmosphere 2.1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / tetrahydrofuran; water / 48 h / Reflux; Inert atmosphere View Scheme
参考文献
Journal of Materials Chemistry, , vol. 21, # 14 p. 5451 - 5456
反应条件
potassium borohydride in ethanol T=20°C; 4 h;
参考文献
Brunel; Ledoux; Zyss; Blanchard-Desce
Chemical Communications, 2001 , # 10 p. 923 - 924
反应条件
1: 64 percent / NaBH4 / tetrahydrofuran; methanol / 20 °C
2: 67 percent / N-chlorosuccinimide; PPh3 / tetrahydrofuran
View Scheme
参考文献
Badjic, Jovica D.; Cantrill, Stuart J.; Stoddart, J. Fraser
Journal of the American Chemical Society, 2004 , vol. 126, # 8 p. 2288 - 2289
反应条件
1: 100 percent / KBH4 / ethanol / 4 h / 20 °C
2: 90 percent / HBr / 5 h / Heating
View Scheme
参考文献
Brunel; Ledoux; Zyss; Blanchard-Desce
Chemical Communications, 2001 , # 10 p. 923 - 924
