sodium hydrogencarbonate in water 0.166667 h; Heating;

1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating 2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating 3: 33.4 percent / Et3N / CH2Cl2 / 1 h / Ambient temperature 4: 85.5 percent / concd. HCl / dioxane / 2 h / Heating 5: 62.7 percent / (NH4)2CO3 / H2O / 65-70 deg C, 24 h then 90 deg C, 1 h 6: 97.1 percent / concd. H2SO4 / benzene / 5 h / Heating View Scheme

1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating 2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating 3: 33.4 percent / Et3N / CH2Cl2 / 1 h / Ambient temperature 4: 85.5 percent / concd. HCl / dioxane / 2 h / Heating 5: 62.7 percent / (NH4)2CO3 / H2O / 65-70 deg C, 24 h then 90 deg C, 1 h View Scheme

1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating 2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating 3: 33.4 percent / Et3N / CH2Cl2 / 1 h / Ambient temperature 4: 85.5 percent / concd. HCl / dioxane / 2 h / Heating View Scheme

1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating 2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating 3: 19.5 percent / Et3N / CH2Cl2 / 1 h / Ambient temperature 4: 92.4 percent / concd. HCl / dioxane / 2 h / Heating View Scheme

Multi-step reaction with 2 steps 1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating  

Multi-step reaction with 3 steps 1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating3: 19.5 percent / Et3N / CH2Cl2 / 1 h / Ambient temperature  

Multi-step reaction with 3 steps 1: 92.1 percent / NaHCO3 / H2O / 0.17 h / Heating2: 91.0 g / SOCl2 / 1,2-dichloro-ethane / 1 h / Heating3: 33.4 percent / Et3N / CH2Cl2 / 1 h / Ambient temperature