hydrogenchloride; sodium tetrahydroborate; acetic anhydride in water incorporation of doubly labelled precursors; (6RS)-D-<6-14C,6-3H>glucose; Mechanism;
参考文献
Goda, Sayed K.; Al-Feel, Walid; Akhtar, Muhammad
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1986 , p. 1383 - 1390
Pinsetta, Flavio Roberto; Kawano, Daniel Fabio; De Carvalho, Marcelo Rodrigues; De Oliveira, Jose Antonio A.; Corrado, Alexandre P.; Hyppolito, Miguel Angelo; Carvalho, Ivone
Carbohydrate Research, 2013 , vol. 373, p. 97 - 102
1.1: hydrogen bromide / 120 h / 100 °C
2.1: sodium azide; potassium carbonate; trifluoromethylsulfonic anhydride / water / 1.5 h
2.2: 18 h
3.1: pyridine; 4-(N,N-dimethlyamino)pyridine / 72 h / 0 - 20 °C
View Scheme
参考文献
Pinsetta, Flavio Roberto; Kawano, Daniel Fabio; De Carvalho, Marcelo Rodrigues; De Oliveira, Jose Antonio A.; Corrado, Alexandre P.; Hyppolito, Miguel Angelo; Carvalho, Ivone
Carbohydrate Research, 2013 , vol. 373, p. 97 - 102
