2-氨基-1-(4-硝基苯基)-1,3-丙二醇合成路线 （共 90 条）
反应条件
1: K2CO3 2: NaBH4 / tetrahydrofuran / Ambient temperature 3: NaN3/silica gel / dimethylformamide / 80 °C 4: H2O, PPh3 / tetrahydrofuran View Scheme
参考文献
Journal of the Chemical Society - Series Chemical Communications, , # 11 p. 859 - 860
反应条件
1: NaN3/silica gel / dimethylformamide / 80 °C 2: H2O, PPh3 / tetrahydrofuran View Scheme
参考文献
Journal of the Chemical Society - Series Chemical Communications, , # 11 p. 859 - 860
反应条件
1: NaBH4 / tetrahydrofuran / Ambient temperature 2: NaN3/silica gel / dimethylformamide / 80 °C 3: H2O, PPh3 / tetrahydrofuran View Scheme
参考文献
Journal of the Chemical Society - Series Chemical Communications, , # 11 p. 859 - 860
反应条件
1.1: lithium perchlorate; diisopropylamine; n-butyllithium / tetrahydrofuran / 1.17 h / -78 - -40 °C / |Inert atmosphere 1.2: 0.25 h / -78 °C / |Inert atmosphere 2.1: hydrogenchloride / water / 3.5 h / 80 °C / |Sealed tube; |Inert atmosphere 3.1: thionyl chloride / 40 °C / |Inert atmosphere 4.1: sodium tetrahydroborate / methanol / 60 °C / |Inert atmosphere View Scheme
参考文献
Chinese Journal of Chemistry, , vol. 31, # 1 p. 149 - 153
反应条件
1: hydrogenchloride / water / 3.5 h / 80 °C / |Sealed tube; |Inert atmosphere 2: thionyl chloride / 40 °C / |Inert atmosphere 3: sodium tetrahydroborate / methanol / 60 °C / |Inert atmosphere View Scheme
参考文献
Chinese Journal of Chemistry, , vol. 31, # 1 p. 149 - 153
反应条件
lithium aluminium tetrahydride; diethyl ether ueber mehrere Stufen;
反应条件
1: 100 percent / DMAP; pyridine 2: HNO3; H2SO4 / 1.5 h / -20 - 20 °C 3: aq. HCl / 90 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 46, # 10 p. 1743 - 1746
反应条件
1: Lg-tartaric acid 2: aqueous HBr / Hydrolysis View Scheme
参考文献
Yakugaku Zasshi, , vol. 72, p. 677,679
Chem.Abstr., , p. 6373
反应条件
hydrogenchloride; water; isopropyl alcohol
反应条件
1: HNO3; H2SO4 / 1.5 h / -20 - 20 °C 2: aq. HCl / 90 °C View Scheme
参考文献
Tetrahedron Letters, , vol. 46, # 10 p. 1743 - 1746
