1,2,3,4-四氢萘合成路线 （共 818 条）
反应条件
1: AlCl3; CS2
2: sulfur / 220 °C
3: palladium coal; propanol-(2); concentrated aqueous HCl / Hydrogenolyse
View Scheme
参考文献
Koelbel
Brennstoff-Chemie, 1949 , vol. 30, p. 73,75
反应条件
1: AlCl3
2: Zn-Hg, aq. HCl / toluene / Heating
3: polyphosphoric acid / Heating
4: LiAlH4 / diethyl ether / Heating
5: KHSO4 / 150 °C
View Scheme
参考文献
Christol,H. et al.
Bulletin de la Societe Chimique de France, 1960 , p. 1576 - 1581
反应条件
1: AlCl3; CS2
2: sulfur / 220 °C
3: palladium; propanol-(2); concentrated aqueous HCl / Hydrogenolyse
View Scheme
参考文献
Koelbel
Brennstoff-Chemie, 1949 , vol. 30, p. 73,75
反应条件
AlCl3, aluminium chloride in dichloromethane
T=0 - 20°C; 4.5 h;
参考文献
KIM, Kong Kyeom; Hong, Sung Kil; Jang, Hye Young; Jeong, Dong Seob
Patent: US2014/77165 A1, 2014 ;
Location in patent: Paragraph 0078-0080 ;
参考文献
Tetralin-Ges.
Patent: DE346673 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 13, p. 387
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Schroeter
Chemische Berichte, 1921 , vol. 54, p. 2248
反应条件
1: AlCl3 / nitrobenzene
2: H2 / (catalytic hydrogenation)
3: polyphosphoric acid
4: Zn-Hg, aq. HCl / toluene; acetic acid
5: Pd-C / 320 - 350 °C
View Scheme
参考文献
Chatterjee,D.N.; Chakravorty,S.R.
Journal of the Indian Chemical Society, 1976 , vol. 53, p. 610 - 616
反应条件
ammonia; sodium in methanol
T=-75 - -33°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Beger, J.; Thomas, B.; Vogel, T.; Kirmse, K.; Lang, R.
Journal fuer Praktische Chemie (Leipzig), 1991 , vol. 333, # 3 p. 481 - 488
反应条件
bei der Nitrierung und Reduktion mit Zink und Saeure und trennt die erhaltenen Amine ueber die Acetylderivate;
参考文献
Schroeter
Justus Liebigs Annalen der Chemie, 1922 , vol. 426, p. 132
Full Text Show Details
Tetralin-Ges.
Patent: DE333157 ;
Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 13, p. 320
反应条件
1: 97 percent / 4-tbutyl iodoxybenzene / chlorobenzene / 6 h / 130 - 140 °C
2: 97 percent / Cl2 / hexane
3: 86 percent / 5N NaOH, Cl2, AcOH / at room temp. 1.5 h then 60-70 deg C, 0.5 h
View Scheme
参考文献
Ranganathan, S.; Ranganathan, D.; Singh, S. K.
Tetrahedron Letters, 1985 , vol. 26, # 40 p. 4955 - 4956
反应条件
XeF2; hydrogen fluoride
参考文献
Sket,B.; Zupan,M.
Journal of Organic Chemistry, 1978 , vol. 43, # 5 p. 835 - 837
