119072-55-8合成路线 （共 225 条）
反应条件
dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct; caesium carbonate in toluene
16 h; Inert atmosphereReflux;
参考文献
Geden, Joanna V.; Pancholi, Alpa K.; Shipman, Michael
Journal of Organic Chemistry, 2013 , vol. 78, # 8 p. 4158 - 4164
反应条件
palladium (II) trifluoroacetate; cupric trifluoroacetate; 2,2,2-trimethylacetic acid in 1,2-dichloro-ethane
T=70°C; 1 h; Sealed tube;
参考文献
Peng, Jiangling; Zhao, Jiaji; Hu, Ziwei; Liang, Dongdong; Huang, Jinbo; Zhu, Qiang
Organic Letters, 2012 , vol. 14, # 18 p. 4966 - 4969,4
反应条件
copper diacetate; palladium diacetate in acetic acid
T=50°C; 12 h; Sealed tube;
参考文献
Peng, Jiangling; Zhao, Jiaji; Hu, Ziwei; Liang, Dongdong; Huang, Jinbo; Zhu, Qiang
Organic Letters, 2012 , vol. 14, # 18 p. 4966 - 4969,4
反应条件
water; triphenylphosphine; cesium fluoride; palladium dichloride in dimethyl sulfoxide
T=90°C;
参考文献
Jiang, Huanfeng; Liu, Bifu; Li, Yibiao; Wang, Azhong; Huang, Huawen
Organic Letters, 2011 , vol. 13, # 5 p. 1028 - 1031
反应条件
potassium fluoride; 18-crown-6 ether; water in tetrahydrofuran
T=30°C; 16 h; Inert atmosphere; Overall yield = 61 percent; Overall yield = 0.060 g; regioselective reaction;
参考文献
Kaicharla, Trinadh; Thangaraj, Manikandan; Biju, Akkattu T.
Organic Letters, 2014 , vol. 16, # 6 p. 1728 - 1731
反应条件
in benzene-d6
byproducts: 1,5-COD; placing of Ru(COD)(CN(t-Bu))3 in NMR tube; introduction of 10 equiv. excess of tert-butylisonitrile and C6D6; warming at 70°C for 2 days; monitoring by NMR;
参考文献
Hirano, Masafumi; Asakawa, Rie; Nagata, Chifumi; Miyasaka, Takashi; Komine, Nobuyuki; Komiya, Sanshiro
Organometallics, 2003 , vol. 22, # 12 p. 2378 - 2386
反应条件
in toluene
byproducts: 1,5-COD, 1,3,5-COT; (N2); using Schlenk techniques; dissolving of Ru(COT)(COD) in toluene, addn. of tert-butylisonitrile; stirring at 50.degre.C for 55 h; removal of all volatile materials under reduced pressure, extn. with a mixt. of acetone and hexane, fractional crystn.;
参考文献
Hirano, Masafumi; Asakawa, Rie; Nagata, Chifumi; Miyasaka, Takashi; Komine, Nobuyuki; Komiya, Sanshiro
Organometallics, 2003 , vol. 22, # 12 p. 2378 - 2386
反应条件
in tetrahydrofuran
N2 atmosphere; addn. of Ru-complex to Na-amalgam and t-BuCN (-50°C), warming to room temp., stirring (48 h); evapn. in vacuo, extn. (hexane), crystn. (-18°C); elem. anal.;
参考文献
Bassett, Jean-Marie; Berry, David E.; Barker, Geoffrey K.; Green, Michael; Howard, Judith A. K.; Stone, F. Gordon A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1003 - 1011
反应条件
(i) Cu2O, benzene, (ii) /BRN= 969135/; Multistep reaction;
参考文献
Ito,Y. et al.
Journal of Organometallic Chemistry, 1977 , vol. 137, p. 1 - 9
反应条件
1: With Ti(NMe2)2(dpma); cyclohexylamine in toluene
T=100°C; 24 h; Inert atmosphere;
2: With hydroxylamine hydrochloride in ethanol; toluene
T=25°C; 16 h; Inert atmosphere; regioselective reaction;
参考文献
Dissanayake, Amila A.; Odom, Aaron L.
Tetrahedron, 2012 , vol. 68, # 3 p. 807 - 812
