carbon monoxide in diethyl ether High Pressure; under nitrogen; autoclave: 70 h at room temperature and 50 atm CO; then 1-2 h at 80-100 °C;; products were isolated by crystallization and chromatography; NMR, IR, MS;
参考文献
Schubert, Ulrich; Kron, Johanna; Hoernig, Hannelore
Journal of Organometallic Chemistry, 1988 , vol. 355, p. 243 - 256
tris-(dibenzylideneacetone)dipalladium(0); C26H25N2P; C26H24NPS; N-ethyl-N,N-diisopropylamine in tetrahydrofuran
T=120°C; Heck reaction; 4 h; Microwave irradiation; optical yield given as percent eeenantioselective reaction;
参考文献
Henriksen, Signe T.; Norrby, Per-Ola; Kaukoranta, Paeivi; Andersson, Pher G.
Journal of the American Chemical Society, 2008 , vol. 130, # 31 p. 10414 - 10421
