in acetonitrile Kinetics; react. of the metal carbonyl anion (0.001 M) with an excess of the Co(III) complex (0.10-0.30 M) at 25°C in CH3CN with addn. of excess (NBu4)(BF4) (0.01-0.04 M); detn. by decrease of the IR intensity of the metal carbonyl anion;
参考文献
Corraine, M. Shauna; Lai, C. K.; Zhen, Yueqian; Churchill, Melvyn Rowen; Buttrey, Lisa A.; et al.
Organometallics, 1992 , vol. 11, p. 35 - 40
in acetonitrile Kinetics; react. of the metal carbonyl anion (0.001 M) with an excess of the Co(III) complex (0.10-0.30 M) at 25°C in CH3CN;; detn. by decrease of the IR intensity of the metal carbonyl anion;;
参考文献
Corraine, M. Shauna; Lai, C. K.; Zhen, Yueqian; Churchill, Melvyn Rowen; Buttrey, Lisa A.; et al.
Organometallics, 1992 , vol. 11, p. 35 - 40
in acetonitrile byproducts: [Re2(CO)10(μ-C2H4)], [(Ph3P)2N][Mn(CO)5]; (N2); glove-box, Schlenk-line technique; solids Re complex and Mn complex were mixed; CH3CN was added; not isolated; IR monitoring;
参考文献
Hoth, David C.; Atwood, Jim D.
Inorganica Chimica Acta, 2002 , vol. 334, p. 71 - 76
