3-甲基-2-环己烯-1-酮合成路线 (共 314 条)
反应条件
(8-oxyquinolinate)2VV(O)(OiPr); triethylamine in 1,2-dichloro-ethane T=80°C; 24 h;
参考文献
Hanson, Susan K.; Wu, Ruilian; Silks, L. A. Pete
Organic Letters, 2011 , vol. 13, # 8 p. 1908 - 1911
反应条件
silver tetrafluoroborate; water in acetic acid T=110°C; 10 h; regioselective reaction;
参考文献
Chen, Zheng-Wang; Ye, Dong-Nai; Qian, Yi-Ping; Ye, Min; Liu, Liang-Xian
Tetrahedron, 2013 , vol. 69, # 30 p. 6116 - 6120
反应条件
tert.-butylhydroperoxide; Rh2(Cap)4; potassium carbonate in dichloromethane 0.333333 h;
参考文献
Catino, Arthur J.; Forslund, Raymond E.; Doyle, Michael P.
Journal of the American Chemical Society, 2004 , vol. 126, # 42 p. 13622 - 13623
反应条件
1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in o-di-fluorobenzene; dimethyl sulfoxide T=65°C; 10 h;
参考文献
Nicolaou; Montagnon; Baran; Zhong
Journal of the American Chemical Society, 2002 , vol. 124, # 10 p. 2245 - 2258
反应条件
tert.-butylhydroperoxide; [ruthenium(II)(terpy)(4′-methyl-2,2′-bipyridine-4-carboxylic acid)Cl]Cl in tert-butyl alcohol T=26°C; Inert atmosphere;
参考文献
Polyhedron, , vol. 52, p. 634 - 638
反应条件
1: methyllithium in diethyl ether T=-78°C; 2: cyclohexenon in diethyl ether T=-78°C; 3: With Mukayama reagent in diethyl ether T=-78°C; 0.5 h;
参考文献
Matsuo, Jun-Ichi; Aizawa, Yayoi
Chemical Communications, 2005 , # 18 p. 2399 - 2401
反应条件
tert.-butylhydroperoxide; Rh2(Cap)4; potassium carbonate in dichloromethane 1 h;
参考文献
Catino, Arthur J.; Forslund, Raymond E.; Doyle, Michael P.
Journal of the American Chemical Society, 2004 , vol. 126, # 42 p. 13622 - 13623
反应条件
Amberlyst 15; sodium iodide in acetone T=20°C; deoxygenation; 3 h;
参考文献
Righi, Giuliana; Bovicelli, Paolo; Sperandio, Anna
Tetrahedron, 2000 , vol. 56, # 12 p. 1733 - 1737
反应条件
dihydrogen peroxide; titanium silicate-1 (Si/Ti=35; MFI structure zeolite) in acetone 3 h; Heating;
参考文献
Joseph; Sudalai; Ravindranathan
Tetrahedron Letters, 1994 , vol. 35, # 30 p. 5493 - 5496
反应条件
FeCl3(5-chlorobenzotriazole)2·2(5-chlorobenzotriazole); dihydrogen peroxide in water; acetonitrile T=26°C; 2 h; Inert atmosphere; Reagent/catalystTime;
参考文献
Polyhedron, , vol. 64, p. 189 - 202