3-甲基-2-环己烯-1-酮合成路线 （共 314 条）
参考文献
Skita; Ritter
Chemische Berichte, 1911 , vol. 44, p. 673
反应条件
ammonium cerium(IV) nitrate; iodine in acetonitrile 10 h; Heating;
参考文献
Horiuchi, C. Akira; Fukunishi, Hirotada; Kajita, Mika; Yamaguchi, Akihisa; Kiyomiya, Hiroshi; Kiji, Shinji
Chemistry Letters, 1991 , # 11 p. 1921 - 1924
反应条件
potassium hydroxide; [bis(acetoxy)iodo]benzene in methanol 1 h; Ambient temperature;
参考文献
Tamura, Yasumitsu; Yakura, Takayuki; Terashi, Hiroaki; Haruta, Jun-Ichi; Kita, Yasuyuki
Chemical & Pharmaceutical Bulletin, 1987 , vol. 35, # 2 p. 570 - 577
反应条件
potassium hydroxide; [bis(acetoxy)iodo]benzene 1 h; Ambient temperature;
参考文献
Tamura, Yasumitsu; Yakura, Takayuki; Terashi, Hiroaki; Haruta, Jun-Ichi; Kita, Yasuyuki
Chemical & Pharmaceutical Bulletin, 1987 , vol. 35, # 2 p. 570 - 577
反应条件
2: 94 percent / LDA / tetrahydrofuran / 1 h / -78 - 25 °C 3: 93 percent / LiCl / (Ph3P)4Pd / dimethylformamide / 1 h / 70 °C View Scheme
参考文献
Krohn, Karsten; Khanbabaee, Karamali
Liebigs Annalen der Chemie, 1994 , # 11 p. 1109 - 1112
反应条件
tetrafluoroboric acid; hydrogen; ruthenium catalyst with atropoisomeric (R)-ligand in water; isopropyl alcohol T=60°C; Catalytic hydrogenation; P=45003.6 Torr; 20 h; Title compound not separated from byproducts;
参考文献
Chae, Junghyun; Yun, Jaesook; Buchwald, Stephen L.
Organic Letters, 2004 , vol. 6, # 26 p. 4809 - 4812
反应条件
hydrogen; HRuCl(TBPC)2 in benzene T=80°C; P=30400 Torr; 22 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Massonneau, Viviane; Maux, Paul Le; Simonneaux, Gerard
Journal of Organometallic Chemistry, 1987 , vol. 327, p. 269 - 274
反应条件
(R)-DTBM-Segphos; [Cu(PPh3)2NO3]; hydrogen; sodium t-butanolate in isopropyl alcohol T=30°C; P=37503.8 Torr; 18 h; optical yield given as percent eeenantioselective reaction;
参考文献
Shimizu, Hideo; Nagano, Takuto; Sayo, Noboru; Saito, Takao; Ohshima, Takashi; Mashima, Kazushi
Synlett, 2009 , # 19 p. 3143 - 3146
反应条件
glucose dehydrogenase; D-glucose; enoate-reductase YQJm from Bacillus subtilis mutant C26D/A104F; nicotinamide adenine dinucleotide phosphate T=30°C; pH=7; 5 h; aq. phosphate bufferEnzymatic reaction; optical yield given as percent ee;
参考文献
Yanto, Yanto; Yu, Hua-Hsiang; Hall, Melanie; Bommarius, Andreas S.
Chemical Communications, 2010 , vol. 46, # 46 p. 8809 - 8811
反应条件
ammonium cerium(IV) nitrate; iodine in acetonitrile 10 h; Heating;
参考文献
Horiuchi, C. Akira; Fukunishi, Hirotada; Kajita, Mika; Yamaguchi, Akihisa; Kiyomiya, Hiroshi; Kiji, Shinji
Chemistry Letters, 1991 , # 11 p. 1921 - 1924
