3-甲基-2-环己烯-1-酮合成路线 （共 314 条）
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide in tetrahydrofuran
T=-78°C; 1 h; Yield given;
参考文献
Nakamura, Eiichi; Matsuzawa, Satoshi; Horiguchi, Yoshiaki; Kuwajima, Isao
Tetrahedron Letters, 1986 , vol. 27, # 34 p. 4029 - 4032
反应条件
in tetrahydrofuran
T=-78°C; 0.0833333 h;
参考文献
Nakamura, Eiichi; Matsuzawa, Satoshi; Horiguchi, Yoshiaki; Kuwajima, Isao
Tetrahedron Letters, 1986 , vol. 27, # 34 p. 4029 - 4032
反应条件
hydrogenchloride; CuI in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide
参考文献
Sterling Winthrop Inc.
Patent: US5306818 A1, 1994 ;
US 5306818 A
反应条件
1: C7H17AlSi With copper(I) thiophene-2-carboxylate; 1,1-bis(3,5-dimethylphenyl)-N,N-bis((S)-1-(naphthalen-2-yl)ethyl)phosphinamine in diethyl ether
T=-30°C; 0.25 h; Inert atmosphere;
2: 3-methyl-cyclohex-2-en-1-one in diethyl ether
T=-30°C; 14 h; Inert atmosphere;
参考文献
Mueller, Daniel; Alexakis, Alexandre
Chemistry - A European Journal, 2013 , vol. 19, # 45 p. 15226 - 15239
反应条件
iodine; magnesium
1.) THF 0 deg C, 1 h; 2.) HMPA, 2 h, R.T.;
参考文献
Andriamialisoa, R. Z.; Fetizon, M.; Hanna, I.
Tetrahedron, 1984 , vol. 40, # 21 p. 4285 - 4296
反应条件
(i) tBuLi, (ii) CuI, (iii) /BRN= 1560601/; Multistep reaction;
参考文献
Boeckman,R.K.; Bruza,K.J.
Journal of Organic Chemistry, 1979 , vol. 44, p. 4781 - 4788
反应条件
(CuOTf)2.C6H6; tributylphosphine in N,N-dimethyl-formamide
T=60°C; 66 h;
参考文献
Ito; Ishizuka; Tateiwa; Sonoda; Hosomi
Journal of the American Chemical Society, 1998 , vol. 120, # 43 p. 11196 - 11197
反应条件
copper(l) iodide
multistep reaction; tertiary amines and HMPA as reagents; Product distribution;
参考文献
Ager, David J.; Fleming, Ian; Patel, Shailesh K.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 2520 - 2526
参考文献
Matsuo, Goh; Miki, Yuko; Nakata, Masaya; Matsumura, Shuichi; Toshima, Kazunobu
Chemical Communications, 1996 , # 2 p. 225 - 226
反应条件
Yield given. Multistep reaction;
参考文献
Krohn, Karsten; Khanbabaee, Karamali
Liebigs Annalen der Chemie, 1994 , # 11 p. 1109 - 1112
