3-甲基-2-环己烯-1-酮合成路线 （共 314 条）
反应条件
C37H31N2O2(1+)*Cl(1-); copper(II) bis(trifluoromethanesulfonate) in diethyl ether
T=0°C; 0.833333 h; Inert atmosphere;
参考文献
Kehrli, Stefan; Martin, David; Rix, Diane; Mauduit, Marc; Alexakis, Alexandre
Chemistry - A European Journal, 2010 , vol. 16, # 32 p. 9890 - 9904
反应条件
(i) H2O2, OH-, (ii) TsNHNH2, AcOH, CH2Cl2; Multistep reaction;
参考文献
Trost, Barry M.; Bartlett, Mark J.; Weiss, Andrew H.; Vonwangelin, Axel Jacobi; Chan, Vincent S.
Chemistry - A European Journal, 2012 , vol. 18, # 51 p. 16498 - 16509
反应条件
1.1: CuI; LiCl / tetrahydrofuran / 0.5 h / 0 °C
1.2: 89 percent / tetrahydrofuran / 1 h / 20 °C
2.1: 62 percent / Zn; TiCl4 / CH2Cl2 / 0.5 h / 20 °C
3.1: oxalyl chloride; DMSO; Et3N / CH2Cl2 / -78 - 20 °C
View Scheme
参考文献
Zhang, Liming; Koreeda, Masato
Organic Letters, 2004 , vol. 6, # 4 p. 537 - 540
反应条件
1: 78 percent / diethyl ether / 4 h / Heating
2: HClO4 / diethyl ether / 0.5 h
View Scheme
参考文献
Zaidlewicz, Marek
Tetrahedron Letters, 1986 , vol. 27, # 42 p. 5135 - 5138
反应条件
Destillation des Reaktionsprodukts;
参考文献
Haworth
Journal of the Chemical Society, 1913 , vol. 103, p. 1249
反应条件
anschliessende Dehydratisierung;
参考文献
Wheeler
Journal of Organic Chemistry, 1955 , vol. 20, p. 1672,1673
Full Text Show Details
Braude et al.
Journal of the Chemical Society, 1956 , p. 4054,4058
参考文献
Levina,R.Ya. et al.
J. Gen. Chem. USSR (Engl. Transl.), 1960 , vol. 30, p. 2145 - 2148,2121 - 2123
反应条件
1: ethanol; platinum / Hydrogenation
View Scheme
参考文献
Woods et al.
Journal of the American Chemical Society, 1949 , vol. 71, p. 2028
反应条件
1: 85 percent / diethyl ether
View Scheme
参考文献
Zaidlewicz, Marek
Tetrahedron Letters, 1986 , vol. 27, # 42 p. 5135 - 5138
反应条件
triethylamine in diethyl ether
3 h; Ambient temperature; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Emde, Herbert; Goetz, Andreas; Hofmann, Karin; Simchen, Gerhard
Liebigs Annalen der Chemie, 1981 , # 9 p. 1643 - 1657
