3-甲基-2-环己烯-1-酮合成路线 （共 314 条）
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; copper(l) iodide; methyllithium; diisobutylaluminium hydride
1.) THF, ether, hexane, -50 degC, 2.) THF, ether, hexane, 0 deg C, 2 h; Yield given. Multistep reaction;
参考文献
Tsuda, Tetsuo; Satomi, Hiroshi; Hayashi, Toshio; Saegusa, Takeo
Journal of Organic Chemistry, 1987 , vol. 52, # 3 p. 439 - 443
参考文献
Mazurewitsch
Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1925 , vol. 56, p. 21
Chem. Zentralbl., 1926 , vol. 97, # I p. 913
反应条件
titanium tetrachloride
Irradiation;
参考文献
Sato,T. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 788 - 791
反应条件
phenylmethylsulfonylbenzene; oxygen; potassium iodide in chlorobenzene
T=140°C; 24 h;
参考文献
Liao, Yunfeng; Jiang, Pengcheng; Chen, Shanping; Xiao, Fuhong; Deng, Guo-Jun
RSC Advances, 2013 , vol. 3, # 40 p. 18605 - 18608
反应条件
titanium tetrachloride
Irradiation;
参考文献
Sato,T. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 788 - 791
反应条件
titanium tetrachloride
Irradiation;
参考文献
Sato,T. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1976 , p. 788 - 791
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; potassium hexamethylsilazane
1.) DMF, THF, -78 deg C, 2 h; 2.) DMF, THF, 20 min, r.t.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Kawanisi, Mituyosi; Itoh, Yasuko; Hieda, Takanori; Kozima, Sinpei; Hitomi, Torazo; Kobayashi, Kazuko
Chemistry Letters, 1985 , p. 647 - 650
反应条件
manganese triacetate in benzene
6 h; Heating;
参考文献
Demir, Ayhan S.; Jeganathan, Alwarsamy; Watt, David S.
Journal of Organic Chemistry, 1989 , vol. 54, # 17 p. 4020 - 4022
反应条件
1: chloro-trimethyl-silane; 3-methyl-cyclohex-2-en-1-one With copper(l) iodide; lithium chloride in tetrahydrofuran
T=-40°C; 0.166667 h; Inert atmosphere;
2: methyl-magnesium chloride in tetrahydrofuran
T=-40°C; 0.75 h;
3: With water; ammonium chloride in tetrahydrofuran
参考文献
Martinez-Solorio, Dionicio; Jennings, Michael P.
Organic Letters, 2009 , vol. 11, # 1 p. 189 - 192
反应条件
copper(l) iodide; lithium chloride in tetrahydrofuran
T=0°C; 0.5 h;
参考文献
Reetz, Manfred T.; Kindler, Alois
Journal of Organometallic Chemistry, 1995 , vol. 502, # 1-2 p. C5 - C7
