3-甲基-2-环己烯-1-酮合成路线 （共 314 条）
反应条件
in hexane T=20°C; Dehydroiodination; 3 h; Irradiation;
参考文献
Tetrahedron Letters, , vol. 40, # 52 p. 9263 - 9266
反应条件
1: 1-Bromo-2-butyne in diethyl ether T=18 - 20°C; Metallation; 2: C13H15NS in diethyl ether T=20°C; Grignard reaction; 15 h; 3: With hydrogenchloride in diethyl ether; water T=20°C; Hydrolysis; 2 h;
参考文献
Barbot, Francis; Aidene, Mohand; Miginiac, Leone
Synthetic Communications, 1998 , vol. 28, # 17 p. 3279 - 3289
反应条件
1: imidazole / Heating 2: 82 percent / diethyl ether / 24 h View Scheme
参考文献
Synthetic Communications, , vol. 12, # 10 p. 795 - 800
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in benzene Heating;
参考文献
Herbert, Nicola; Pattenden, Gerald
Synlett, 1997 , vol. 1997, # 1 p. 69 - 70
反应条件
1: 1-bromo-3-methyl-1-butyne in diethyl ether T=18 - 20°C; Metallation; 2: C13H15NS in diethyl ether T=20°C; Grignard reaction; 15 h; 3: With hydrogenchloride in diethyl ether; water T=20°C; Hydrolysis; 2 h;
参考文献
Barbot, Francis; Aidene, Mohand; Miginiac, Leone
Synthetic Communications, 1998 , vol. 28, # 17 p. 3279 - 3289
反应条件
2-hydroxy-1,3-isoindolinedione in pyridine; acetonitrile electrochemical oxidation; Mechanism;
参考文献
Chemical and Pharmaceutical Bulletin, , vol. 33, # 11 p. 4798 - 4802
反应条件
1: 3-ethoxy-2-cyclohexen-1-one With 1,1,1,2,2,2-hexabutyl-distannane in tetrahydrofuran 2: With n-butyllithium in tetrahydrofuran 3: methyl iodide With cesium fluoride; tris-(o-tolyl)phosphine; copper(I) bromide; tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran Stille coupling;
参考文献
Organic and Biomolecular Chemistry, , vol. 4, # 3 p. 410 - 415
反应条件
1: 68 percent / p-toluenesulfonic acid monohydrate / benzene / 4 h / Heating 2: 1.) n-BuLi / 1.) THF, -78 deg C, 0.5 h, 2.) a) -78 deg C, 1 h, b) RT, 1 h View Scheme
参考文献
Journal of Organic Chemistry, , vol. 47, # 15 p. 2825 - 2832
反应条件
C34H35N3O2(2-)*Cl(1-)*Fe(3+); dihydrogen peroxide in acetonitrile T=20°C; 4 h; Inert atmosphere;
参考文献
Catalysis Today, , vol. 157, # 1-4 p. 101 - 106
反应条件
Dowex-50 in water 12 h; Heating;
参考文献
Basu, Manas K.; Sarkar, Dipak C.; Ranu, Brindaban C.
Synthetic Communications, 1989 , vol. 19, # 3and4 p. 627 - 632
