2-甲基-1,3-环己二酮合成路线 （共 134 条）
反应条件
triethylamine in ethyl acetate
15 h; Heating;
参考文献
Uma, R.; Rajagopalan, K.; Swaminathan, S.
Tetrahedron, 1986 , vol. 42, # 10 p. 2757 - 2770
反应条件
tributylphosphine in acetonitrile
T=20°C; 10 h;
参考文献
Nakashita, Yoshihiko; Watanabe, Toshio; Benkert, Erwin; Lorenzi-Riatsch, Annalaura; Hesse, Manfred
Helvetica Chimica Acta, 1984 , vol. 67, p. 1204 - 1207
反应条件
1.1: pyridine / dichloromethane / 0.33 h / -78 - 20 °C / |Inert atmosphere
1.2: 1.33 h / -78 - 0 °C / |Inert atmosphere
2.1: tetrahydrofuran / -78 - 20 °C
View Scheme
参考文献
Lisboa, Marilda P.; Hoang, Tung T.; Dudley, Gregory B.
Organic Syntheses, 2012 , vol. 88, p. 353 - 363
反应条件
1: 85 percent / t-BuOK / 2-methyl-propan-2-ol / 96 h / 60 °C
2: 98 percent / NaBH4 / methanol / 0 °C
View Scheme
参考文献
Laverde Jr., Antonio; Da Conceicao, Gelson J. A.; Queiroz, Sonia C. N.; Fujiwara, Fred Y.; Marsaioli, Anita J.
Magnetic Resonance in Chemistry, 2002 , vol. 40, # 7 p. 433 - 442
反应条件
1: Et3N / diethyl ether / 20 h / 20 °C
2: (i) pyrrolidine, benzene, (ii) aq. HCl
View Scheme
参考文献
Molines,H.; Wakselman,C.
Tetrahedron, 1976 , vol. 32, p. 2099 - 2103
反应条件
triethylamine in diethyl ether
T=20°C; 20 h;
参考文献
Molines,H.; Wakselman,C.
Tetrahedron, 1976 , vol. 32, p. 2099 - 2103
参考文献
Batsomboon, Paratchata; Gold, Brian A.; Alabugin, Igor V.; Dudley, Gregory B.
Synthesis (Germany), 2012 , vol. 44, # 12 art. no. SS-2012-C0221-ST, p. 1818 - 1824
参考文献
Yan, Jun; Travis, Benjamin R.; Borhan, Babak
Journal of Organic Chemistry, 2004 , vol. 69, # 26 p. 9299 - 9302
反应条件
1: in methanol
4 h; Heating;
2: in benzene
16 h; Heating; Further stages.;
参考文献
Kawanami, Hajime; Ikushima, Yutaka
Tetrahedron Letters, 2004 , vol. 45, # 26 p. 5147 - 5150
反应条件
toluene-4-sulfonic acid in benzene
28 h; Heating;
参考文献
Banerjee, Ajoy K.; Hurtado S., Hector E.
Tetrahedron, 1985 , vol. 41, # 15 p. 3029 - 3032
