双(四甲基环戊二烯基)二氯化锆合成路线 （共 5 条）
反应条件
C5H2Me4; BuLi; HCl in hexane; water; toluene stirring (room temp., 1 h, vac.), ZrCl4 addn., refluxing (Ar-atmosphere), HCl (aq) addn.; filtering, recrystn. (toluene);
参考文献
Hiller, Joerg; Thewalt, Ulf; Polasek, Miroslav; Petrusova, Lidmila; Varga, Vojtech; Sedmera, Petr; Mach, Karel
Organometallics, 1996 , vol. 15, # 17 p. 3752 - 3759
反应条件
in tetrahydrofuran molar ratio Li(C5Me4H)/ZrCl4 = 2:1;
参考文献
Courtot, P.; Pichon, R.; Salaun, J. Y.; Toupet, L.
Canadian Journal of Chemistry, 1991 , vol. 69, # 4 p. 661 - 672
反应条件
in not given byproducts: hydrazine; Zr complex treated with ligand;
参考文献
Bernskoetter, Wesley H.; Pool, Jaime A.; Lobkovsky, Emil; Chirik, Paul J.
Journal of the American Chemical Society, 2005 , vol. 127, # 21 p. 7901 - 7911
反应条件
in not given byproducts: hydrazine; Zr complex treated with ligand;
参考文献
Bernskoetter, Wesley H.; Pool, Jaime A.; Lobkovsky, Emil; Chirik, Paul J.
Journal of the American Chemical Society, 2005 , vol. 127, # 21 p. 7901 - 7911
反应条件
in toluene byproducts: (CH3)2SnCl2; (N2); using Schlenk techniques; addn. of Me2Sn(C5Me4H-1)2 to ZrCl4 in toluene; stirring under reflux for 24 h; evapn.; addn. of hexane; filtration, concn.; cooling; crystn., elem. anal.;
参考文献
Gomez-Ruiz, Santiago; Prashar, Sanjiv; Fajardo, Mariano; Antinolo, Antonio; Otero, Antonio
Journal of Organometallic Chemistry, 2007 , vol. 692, # 14 p. 3057 - 3064
