2-甲氧基-4,4,5,5-四甲基-1,3,2-二氧硼戊环合成路线 （共 52 条）
反应条件
catalyst: PPh3; Cs2CO3 in tetrahydrofuran; methanol ligand and B comps. (1:1.2 molar ratio) at 70°C for 6-15 h; NMR;
参考文献
Sole, Cristina; Gulyas, Henrik; Fernandez, Elena
Chemical Communications, 2012 , vol. 48, # 31 p. 3769 - 3771
反应条件
(DippNacnac)MgnBu in benzene-d6 T=25°C; 0.5 h;
参考文献
Arrowsmith, Merle; Hill, Michael S.; Hadlington, Terrance; Kociok-Koehn, Gabriele; Weetman, Catherine
Organometallics, 2011 , vol. 30, # 21 p. 5556 - 5559
反应条件
Ru(H)2(H2)(CO)PCy3 in benzene-d6 P=760.051 Torr; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 51, # 7 p. 1671 - 1674
反应条件
C35H73BN6P2 T=60°C; P=3800.26 Torr; 66 h; Inert atmosphere; Reagent/catalystTimeConcentrationTemperature; Overall yield = 100 percent;
参考文献
Chemistry - A European Journal, , vol. 20, # 11 p. 3036 - 3039
反应条件
C27H53BN2P2 T=60°C; P=3800.26 Torr; 114 h; Inert atmosphere; Overall yield = 95 percent;
参考文献
Chemistry - A European Journal, , vol. 20, # 11 p. 3036 - 3039
反应条件
(tBuPOCOP)NiH in benzene-d6 room temp., 1 h;
参考文献
Journal of the American Chemical Society, , vol. 132, # 26 p. 8872 - 8873
反应条件
catalyst: PPh3; Cs2CO3 in tetrahydrofuran; methanol ligand and B comps. (1:1.2 molar ratio) at 70°C for 6-15 h; NMR;
参考文献
Sole, Cristina; Gulyas, Henrik; Fernandez, Elena
Chemical Communications, 2012 , vol. 48, # 31 p. 3769 - 3771
反应条件
1: formic acid; 4,4,5,5-tetramethyl-[1,3,2]dioxaborolane in benzene-d6 T=20°C; 20 h; Inert atmosphere; 2: [RuH2(η2-H2)2(PCy3)2] in benzene-d6 0.166667 h; Inert atmosphere;
参考文献
Angewandte Chemie - International Edition, , vol. 52, # 39 p. 10253 - 10255
反应条件
1: benzene-d6 / 20 h / |Inert atmosphere 2: [RuH2(η2-H2)2(tricyclopentylphosphine)2] / 24 h / |Inert atmosphere View Scheme
参考文献
Journal of the American Chemical Society, , vol. 136, # 11 p. 4419 - 4425
反应条件
catalyst: (CH(C(CH3)N(C6H3(CH(CH3)2)2))2)Mg(C4H9) in not given addn. of 1:1 mixt. of pinacolborane and pyridine deriv. to soln. of magnesium compd., keeping at 25°C for 0.5 h; NMR;
参考文献
Organometallics, , vol. 30, # 21 p. 5556 - 5559
