palladium diacetate; caesium carbonate; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene in 1,4-dioxane T=60°C; 24 h; Inert atmosphere; chemoselective reaction;

1: 4-chlorophenyl 1H-imidazole-1-sulfonate; 3,4,5-trimethoxyphenylboronic acid With C26H16Cl6N2O2Pd2; tetrabutylammomium bromide; potassium hydroxide in methanol; water T=110°C; 0.5 h; Microwave irradiationair; 2: p-methylphenylboronic acid With C26H16Cl6N2O2Pd2; tetra(n-butyl)ammonium hydroxide; potassium carbonate in N,N-dimethyl-formamide T=0 - 110°C; 0.5 h; air;

C26H16Cl6N2O2Pd2; tetrabutylammomium bromide in methanol; water T=110°C; Suzuki coupling; 0.5 h; Microwave irradiation;

N-hexadecyl-N,N,N-trimethylammonium bromide; palladium; triethylamine in water T=110°C; Suzuki-Miyaura Coupling; 0.5 h; Microwave irradiation; Reagent/catalyst;

SPhos; C16H16Cl2N2O4Pd2; N-hexadecyl-N,N,N-trimethylammonium bromide; triethylamine in water T=130°C; Sonogashira Cross-Coupling; 0.5 h; Microwave irradiation;

1: 4-chlorophenyl 1H-imidazole-1-sulfonate; 3,4,5-trimethoxyphenylboronic acid With C26H16Cl6N2O2Pd2; tetrabutylammomium bromide; potassium hydroxide in methanol; water T=110°C; 0.5 h; Microwave irradiationair; 2: p-methylphenylboronic acid With C26H16Cl6N2O2Pd2; tetra(n-butyl)ammonium hydroxide; potassium carbonate in N,N-dimethyl-formamide T=0 - 110°C; 0.5 h; air;

palladium diacetate; caesium carbonate; 1,2-bis-(diphenylphosphino)ethane in 1-methyl-pyrrolidin-2-one T=100°C; 15 h; Inert atmosphere;

palladium diacetate; caesium carbonate; 1,2-bis-(diphenylphosphino)ethane in 1-methyl-pyrrolidin-2-one T=100°C; 15 h; Inert atmosphere;

SPhos; C16H16Cl2N2O4Pd2; N-hexadecyl-N,N,N-trimethylammonium bromide; triethylamine in water T=130°C; Sonogashira Cross-Coupling; 0.5 h; Microwave irradiation;