1: 4'-iodoacetophenone With indium; n-tridecane; lithium chloride in tetrahydrofuran T=50°C; 24 h; 2: 4-iodobenzoic acid ethyl ester With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=40°C; 4 h; Inert atmosphere;

1: With [resin-CH2N(CH3)3]2CO3; Pd(PAnPh2)2Cl2 in water; N,N-dimethyl-formamide T=80°C; Suzuki coupling; 16 h; 2: With maleimido-CH2-PS resin in water; N,N-dimethyl-formamide T=90°C; 10 h;

[(P{(NC5H10)(C6H11)2})2Pd(Cl)2] in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=100°C; Negishi cross-coupling reaction; 0.166667 h; In air;

potassium phosphate; 1,1'-bis(diphenylphosphanyl)ferrocenenickel(II) chloride in toluene T=110°C; Suzuki-Miyaura Coupling; 24 h; Schlenk technique;

water; triethylamine; Pd(OAc)2EnCatTM in N,N-dimethyl-formamide T=120°C; Suzuki-Miyaura reaction; 0.25 h; microwave irradiation;

1: potassium hydroxide / tetrahydrofuran / 20 °C 2: 1,1'-bis(diphenylphosphanyl)ferrocenenickel(II) chloride; potassium phosphate / toluene / 24 h / 110 °C / |Schlenk technique View Scheme