catalyst: Ni(COD)2-Ph2P(CH2)3PPh2 in toluene
alkynylstannane and 1,2-diene (molar ratio 1:3) reacted in toluene in presence of Ni complex (0.05 equiv.) and phosphine (0.05 equiv.) at 50°C for 60 h; detd. by (119)Sn NMR spectra;
in neat (no solvent)
heating (vac., 150°C); elem. anal.;
参考文献
Bogoradovskii, E. T.; Cherkasov, V. N.; Zavgorodnii, V. S.; Rogozev, B. I.; Petrov, A. A.
Journal of General Chemistry USSR (English Translation), 1980 , vol. 50, p. 1641 - 1649
Zhurnal Obshchei Khimii, 1980 , vol. 50, p. 2031 - 2040
in tetrahydrofuran
with exclusion of air and moisture, 1 equiv. of Ph3B soln. in THF was added to Sn-compd. soln. in THF at room temp., 30-60 min; solvent was removed;
参考文献
Wrackmeyer, Bernd; Tok, Oleg L.; Milius, Wolfgang
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2007 , vol. 62, # 12 p. 1509 - 1513
lt;η3-C3H5Pd(PPh3)2gt;+*Cl- in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 4 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 4 p. 828 - 833
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 4 p. 912 - 918
tetrakis(triphenylphosphine) palladium(0) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 6 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1982 , vol. 266, p. 345 - 348
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 266, # 4 p. 862 - 866
lt;η3-C3H5Pd(PPh3)2gt;+*Cl- in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 4 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 4 p. 828 - 833
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 4 p. 912 - 918
tetrakis(triphenylphosphine) palladium(0) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 6 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1982 , vol. 266, p. 345 - 348
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 266, # 4 p. 862 - 866
lt;η3-C3H5Pd(PPh3)2gt;+*Cl- in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 4 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 4 p. 828 - 833
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 4 p. 912 - 918
tetrakis(triphenylphosphine) palladium(0) in N,N,N',N',N'',N''-hexamethylphosphoric triamide
T=20°C; 6 h;
参考文献
Bumagin, N. A.; Kasatkin, A. N.; Beletskaya, I. P.
Doklady Chemistry, 1982 , vol. 266, p. 345 - 348
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 266, # 4 p. 862 - 866
