反应条件
1: indole With Benzoic acid (S)-1-[(S)-5-oxo-2-phenyl-3-(toluene-4-sulfonyl)-[1,3,2]oxazaborolidin-4-yl]-ethyl ester in diethyl ether
T=-85°C; Friedel Crafts alkylation; 24 h; Inert atmosphere;
2: hex-4-en-3-one With diethyl ether
T=-85°C; Friedel Crafts alkylation; 20 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Adachi, Shinya; Tanaka, Fumi; Watanabe, Kazuya; Watada, Atsushi; Harada, Toshiro
Synthesis, 2010 , # 15 art. no. Z12810SS, p. 2652 - 2669
