3-甲基-9-苯基-9H-咔唑合成路线 （共 3 条）
反应条件
tetra-n-butylammonium difluorotriphenylsilicate(IV) in ethylene glycol dimethyl ether
参考文献
Chakrabarty, Shyamal; Chatterjee, Indranil; Tebben, Ludger; Studer, Armido
Angewandte Chemie - International Edition, 2013 , vol. 52, # 10 p. 2968 - 2971
Angew. Chem., 2013 , vol. 125, # 10 p. 3041 - 3044
反应条件
1: potassium tert-butylate; [2,2']bipyridinyl; copper(l) iodide / toluene / 24 h / 100 °C / |Inert atmosphere; |Sealed tube 2: Cu(I)[(CH3CN)4]BF4; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; 2,9-dimethyl-1,10-phenanthroline; iodine; methyloxirane / tetrahydrofuran / 20 h / 20 °C / |Flow reactor; |Inert atmosphere; |Irradiation View Scheme
参考文献
Hernandez-Perez, Augusto C.; Collins, Shawn K.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12696 - 12700
Angew. Chem., 2013 , vol. 125, # 48 p. 12928 - 12932
反应条件
Cu(I)[(CH3CN)4]BF4; 2,9-dimethyl-1,10-phenanthroline; iodine; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; methyloxirane in tetrahydrofuran T=20°C; 20 h; Flow reactorInert atmosphereIrradiation; Catalytic behavior; Overall yield = 70 percent; Overall yield = 34 mg;
参考文献
Hernandez-Perez, Augusto C.; Collins, Shawn K.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 48 p. 12696 - 12700
Angew. Chem., 2013 , vol. 125, # 48 p. 12928 - 12932
