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乙二醇
甲醛
63148-62-9
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二甲基亚砜
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471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
120346-46-5
合成路线
(共 16 条)
200055-89-6
→
反应条件
120346-46-5
反应条件
bis(tri-o-tolylphosphine) palladium(II) chloride; sodium carbonate in tetrahydrofuran T=60°C; Negishi Coupling; 24 h; Schlenk technique;
参考文献
Shah, Parin; Santana, M. Dolores; Garcia, Joaquin; Serrano, J. Luis; Naik, Minal; Pednekar, Suhas; Kapdi, Anant R.
Tetrahedron, 2013 , vol. 69, # 5 p. 1446 - 1453
531-81-7
香豆素-3-羧酸
+
1765-93-1
4-氟苯硼酸
→
反应条件
120346-46-5
反应条件
1,10-phenanthroline; oxygen; palladium diacetate in N,N-dimethyl-formamide T=100°C; 24 h; Sealed tube; regioselective reaction;
参考文献
Khoobi, Mehdi; Molaverdi, Fatemeh; Alipour, Masoumeh; Jafarpour, Farnaz; Foroumadi, Alireza; Shafiee, Abbas
Tetrahedron, 2013 , vol. 69, # 52 p. 11164 - 11168
1765-93-1
4-氟苯硼酸
+
200055-89-6
→
反应条件
120346-46-5
反应条件
bis(tri-o-tolylphosphine) palladium(II) chloride; sodium carbonate in tetrahydrofuran Suzuki-Miyaura Coupling; 24 h; RefluxSchlenk technique;
参考文献
Shah, Parin; Santana, M. Dolores; Garcia, Joaquin; Serrano, J. Luis; Naik, Minal; Pednekar, Suhas; Kapdi, Anant R.
Tetrahedron, 2013 , vol. 69, # 5 p. 1446 - 1453
6236-69-7
+
460-00-4
对溴氟苯
→
反应条件
120346-46-5
反应条件
tetrabutylammomium bromide; tetra-n-butylammonium acetate; palladium diacetate T=100°C; Heck reaction; 24 h;
参考文献
Battistuzzi, Gianfranco; Cacchi, Sandro; De Salve, Ilse; Fabrizi, Giancarlo; Parisi, Luca M.
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 2-3 p. 308 - 312
100379-82-6
+
181705-93-1
4-氟苯溴化锌
→
反应条件
120346-46-5
反应条件
Cl2Ni(1,2-bis(diphenylphosphino)ethane) in benzene T=25°C; 1 h;
参考文献
Wu; Yang
Journal of Organic Chemistry, 2001 , vol. 66, # 23 p. 7875 - 7878
→
反应条件
120346-46-5
反应条件
tetrakis(triphenylphosphine) palladium(0); caesium carbonate in water; toluene T=80°C; Suzuki-Miyaura cross-coupling; 12 h;
参考文献
Wu, Jie; Zhang, Liang; Xia, Hong-Guang
Tetrahedron Letters, 2006 , vol. 47, # 10 p. 1525 - 1528
437-29-6
+
938-40-9
→
反应条件
120346-46-5
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium phosphate in N,N-dimethyl acetamide T=90°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Venkatesh, Varadhachari; Jadhav, Deepak N.
European Journal of Organic Chemistry, 2010 , # 20 p. 3945 - 3955
437-29-6
+
113777-29-0
→
反应条件
120346-46-5
反应条件
bis-triphenylphosphine-palladium(II) chloride; potassium phosphate in N,N-dimethyl acetamide T=90°C; 2 h; Inert atmosphere;
参考文献
Rao, Maddali L. N.; Venkatesh, Varadhachari; Jadhav, Deepak N.
European Journal of Organic Chemistry, 2010 , # 20 p. 3945 - 3955
352-34-1
→
反应条件
120346-46-5
反应条件
tris-(dibenzylideneacetone)dipalladium(0); copper(l) iodide; triphenyl-arsane in N,N-dimethyl-formamide T=60°C; 1 h;
参考文献
Ciattini; Morera; Ortar
Synthetic Communications, 1995 , vol. 25, # 18 p. 2883 - 2894
→
反应条件
120346-46-5
反应条件
1: 4-fluorophenyl boronic acid With potassium carbonate in tetrahydrofuran; water Suzuki Coupling; 0.0833333 h; Inert atmosphere; 2: 2-oxo-2H-chromen-4-yl 4-nitrobenzenesulfonate With dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II) dichloromethane adduct in tetrahydrofuran; water T=30°C; Suzuki-Miyaura Coupling; 3 h; Inert atmosphere;
参考文献
Cheval, Nicolas P.; Dikova, Anna; Blanc, Aurelien; Weibel, Jean-Marc; Pale, Patrick
Chemistry - A European Journal, 2013 , vol. 19, # 27 p. 8765 - 8768
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