H2O in water hydrolysis; formation of H3PO2, H3PO3, H3PO4, phosphines and H2;;
参考文献
Treadwell, W. D.; Beeli, C.
Helvetica Chimica Acta, 1935 , vol. 18, p. 1161 - 1171
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Gmelin Handbook: P: MVol.C, 251, page 573 - 576
I2 in carbon disulfide
byproducts: PI3; react. of iodine in CS2 with P4S3;;
参考文献
Treadwell, W. D.; Beeli, C.
Helvetica Chimica Acta, 1935 , vol. 18, p. 1161 - 1171
Full Text Show Details
Gmelin Handbook: P: MVol.C, 251, page 573 - 576
in neat (no solvent)
condensation of dry H2S-gas on freshly distilled PCl3; storing the soln. for 60-70 h under pressure;; evapn.; fractionated extract. with CS2;;
参考文献
Pitochelli, A. R.; Audrieth, L. F.
Journal of the American Chemical Society, 1959 , vol. 81, p. 4458 - 4460
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Pitochelli, A. R.
Diss. Univ. of Illinois 1958
in carbon disulfide
dissolving P4S3 and S in CS2 and heating up to 170-200°C under pressure;; mechanical separation; recrystn;;
参考文献
Pitochelli, A. R.; Audrieth, L. F.
Journal of the American Chemical Society, 1959 , vol. 81, p. 4458 - 4460
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Pitochelli, A. R.
Diss. Univ. of Illinois 1958
melt of 1:1 molar mixture heated at 250°C for 30 min; further products; not isolated (multidimensional and MAS-(31)P NMR identification); ratio (mol percent) - 1 : 2 : 19 : 5 : 3 : 12 : 3 (depends on P4S3 : S ratio);
参考文献
Bjorholm; Jakobsen
Journal of the American Chemical Society, 1991 , vol. 113, # 1 p. 27 - 32
