(K-18-crown-6 ether) cyanide in diethyl ether
T=20°C; 720 h;
参考文献
Gostevskii, B. A.; Vyazankina, O. A.; Kalikhman, I. D.; Bannikova, O. B.; Vyazankin, N. S.
J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 9 p. 2051 - 2054,1851 - 1854
Gostevskii, B. A.; Kalikhman, I. D.; Vyazankina, O. A.; Bannikova, O. B.; Vyazankin, N. S.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 6 p. 1428 - 1429,1274 - 1275
Gostevskii, B. A.; Kalikhman, I. D.; Vyazankina, O. A.; Bannikova, O. B.; Vyazankin, N. S.
J. Gen. Chem. USSR (Engl. Transl.), 1984 , vol. 54, # 6 p. 1428 - 1429,1274 - 1275
in dimethyl sulfoxide
byproducts: (CH3)3SiF; HgF2 suspended in DMSO in a Schlenk-tube and (CH3)3SiC5F5 added to this soln. at room temp.; reacted for 48-72 h; solid precipitate filtered and washed with DMSO; filtrate and washing liquid added to water; precipitate collected by filtration and dried over concentrated H2SO4;
参考文献
Naumann, Dieter; Schulz, Frank
Zeitschrift fur Anorganische und Allgemeine Chemie, 2005 , vol. 631, # 1 p. 122 - 125
in dimethyl sulfoxide
byproducts: (CH3)3SiF, C6F5H; Hg2F2 suspended in DMSO in a Schlenk-tube and (CH3)3SiC5F5 added to thissoln. at room temp.; reacted for three weeks; low yield; organomercury(I)-compound not detected;
参考文献
Naumann, Dieter; Schulz, Frank
Zeitschrift fur Anorganische und Allgemeine Chemie, 2005 , vol. 631, # 1 p. 122 - 125
