4,6-二甲基二苯并噻吩合成路线 （共 26 条）
反应条件
1: dibenzothiophene With n-butyllithium; N,N,N',N,-tetramethylethylenediamine in hexane T=-78°C; 2: methyl iodide
参考文献
Tetrahedron, , vol. 69, # 1 p. 207 - 211
反应条件
1: With sodium hydroxide in water T=300°C; 1.5 h; Autoclave; 2: With hydrogenchloride in monofluorodichloromethane; water pH=7; Product distribution / selectivity;
参考文献
WO2011/56941 A1, ;
Page/Page column 21-22 ;
反应条件
T=285°C; 0.366667 h;
参考文献
Tetrahedron, , vol. 53, # 17 p. 6073 - 6084
反应条件
diphosphorus pentasulfide T=410°C;
参考文献
Chemische Berichte, , vol. 87, p. 1469,1475
反应条件
1: 95 percent / BBr3 / CH2Cl2 / 4 h / -78 - 20 °C 2: 85 percent / NaH / dimethylformamide / 1 h / 85 °C 3: 20 percent / 0.37 h / 285 °C View Scheme
参考文献
Tetrahedron, , vol. 53, # 17 p. 6073 - 6084
反应条件
sodium hydroxide; selenium; PPA; bromine Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Heterocyclic Chemistry, , vol. 20, p. 1485 - 1495
反应条件
n-butyllithium 1) THF, Et2O, hexane, reflux, 1 h, 2) reflux, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 79, # 1,4 p. 113 - 122
反应条件
hydrogen; Co-Mo-Al (sulfided) T=360°C; P=40503.2 Torr; other supported catalysts Co-Mo and Ni-Mo also with zeolites; Rate constantProduct distributionMechanism;
参考文献
Manoli; Da Costa; Brun; Vrinat; Mauge; Potvin
Journal of Catalysis, 2004 , vol. 221, # 2 p. 365 - 377
反应条件
hydrogen in N-dodecane T=320°C; P=41372.9 Torr; 8 h; Flow reactor;
参考文献
Martinez-Belmonte; Aguilar; Gutierrez; Montoya; De Los Reyes; Torres; Chen
Catalysis Today, 2013 , vol. 212, p. 45 - 51
反应条件
hydrogen sulfide; cobalt molybdenum T=340°C; P=262.521 Torr; Product distributionKinetics; Further Variations:Catalysts;
参考文献
Koizumi, Naoto; Hamabe, Yusuke; Yoshida, Shohei; Yamada, Muneyoshi
Applied Catalysis A: General, 2010 , vol. 383, # 1-2 p. 79 - 88
