三羰基(η-环戊二烯基)合锰合成路线 （共 55 条）
反应条件
CO; H2 in not given High Pressure; 250 bar CO/H2, 105.+/-.5°C, 20 h;
参考文献
Journal of Organometallic Chemistry, , vol. 264, # 3 p. 327 - 352
反应条件
in toluene carried out with exclusion of air and moisture; 1 equiv of AgPF6 added to a stirred soln. of the Pd complex; mixt. stirred for further 20 min. at room temp.; volume reduced in vac., pentane added, filtered through silanized silica gel, elution with CH2Cl2, crystn. from CH2Cl2-Et2O (1:1) at -30°C; elem. anal.;
参考文献
Organometallics, , vol. 10, p. 3861 - 3873
反应条件
in hexane at 20°C under Ar, 1 h; evapn., chromy. (Al2O3, hexane/ether, then ether), recrystn. (hexane/ether)., elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 244, # 1 p. 35 - 46
反应条件
HCk in diethyl ether byproducts: LiCl; Ar atmosphere; addn. of LiAlH4 in ether to soln. of Mn-complex (-60°C), stirring (-60°C, 30 min and at -20°C for 30 min), neutralization (HCl in ether); sepn. of LoCl (filtration), evapn. (vac.), chromy. (5°C, petroleum ether/CH2Cl2 (2:1), petroleum ether/ether (2:1));
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 31, p. 1243 - 1246
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 31, p. 1395 - 1399
反应条件
in toluene Irradiation (UV/VIS); (argon); irradiation at -30°C for 20 min; solvent removal (vac., room temp.), dissoln. (pentane), chromy. (SiO2; CH2Cl2/Et2O/pentane, -20°C), evapn. (vac.); sepn. of one diastereomer is possible by chromy.; elem. anal.;
参考文献
Chemische Berichte, , vol. 129, # 4 p. 385 - 390
反应条件
in toluene Inert atmosphereSchlenk technique;
参考文献
Chemistry - A European Journal, , vol. 20, # 8 p. 2175 - 2178
反应条件
carbon monoxide in not given under CO at 20.5°C; amt. of adsorbed CO detected by gas volumetry; detected spectroscopically;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 19 p. 1249 - 1250
反应条件
in toluene carried out with exclusion of air and moisture; 1 equiv of AgPF6 added to a stirred soln. of the Pd complex; mixt. stirred for further 20 min. at room temp.; volume reduced in vac., pentane added, filtered through silanized silica gel, elution with CH2Cl2, crystn. from CH2Cl2-Et2O (1:1) at -30°C; elem. anal.;
参考文献
Organometallics, , vol. 10, p. 3861 - 3873
反应条件
in dichloromethane (N2, Schlenk technique); complex is warmed to room temp.; chromy. on silica gel (EtOAc);
参考文献
Organometallics, , vol. 13, p. 843 - 865
反应条件
carbon monoxide in gaseous matrix Kinetics;
参考文献
Journal of Physical Chemistry, , vol. 96, # 19 p. 7650 - 7656
