三羰基(η-环戊二烯基)合锰合成路线 （共 55 条）
反应条件
in n-heptane Kinetics; at 298-323 K; time-resolved infrared anal.;
参考文献
Journal of the Chemical Society, Dalton Transactions, , # 12 p. 1901 - 1906
反应条件
in tetrahydrofuran 3 h, reflux;;
参考文献
Angewandte Chemie, , vol. 83, p. 360 - 361
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1706 - 1711
反应条件
in dichloromethane Ar atmosphere; stirring (20°C, 6 h); evapn. (vac.), extn. (CHCl3), chromy. (SiO2, petroleum ether, petroleumether/CHCl3 50:1, 5:1 and 2:1); elem anal.;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 33, p. 1052 - 1058
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 33, p. 1146 - 1152
反应条件
in benzene under Ar; stirred at 70°C for 30 min; filtration (0.5 cm Al2O3), concn. in vac., chromy. (Al2O3, hexane-benzene), elem. anal.;
参考文献
Russian Chemical Bulletin, , vol. 49, # 3 p. 526 - 532
反应条件
in dichloromethane Schlenk technique; in boiling CH2Cl2;
参考文献
Journal of Organometallic Chemistry, , vol. 621, # 1-2 p. 344 - 351
反应条件
in tetrahydrofuran (N2); addn. of the Mn complex to the Fe complex salt in THF with stirring at -90°C, further stirring (-90 to -80°C, 1 h), warming to -50°C over 3 h; evapn. to dryness (high vac., -40°C), chromy. (-25°C, neutral alumina; light petroleum/CH2Cl2, then light petroleum/CH2Cl2/Et2O); elem. anal.;
参考文献
Journal of the Chemical Society - Dalton Transactions, , # 7 p. 1443 - 1447
反应条件
in acetone addn. of Mn(CO)3(C5H4I) to Pd(PPh3)4 in acetone-d6 for 30 min; pouring into Et2O; pptn., dissolution of ppt. into CHCl3; crystn.;
参考文献
Organometallics, , vol. 26, # 15 p. 3887 - 3890
反应条件
in acetone treatment of stoich. amts. of Mn(CO)3(C5H4I) with Pd(PPh3)4 in acetone-d6 in NMR tube for 4 h 15 min; monitoring by NMR; crystn.;
参考文献
Organometallics, , vol. 26, # 15 p. 3887 - 3890
反应条件
in tetrahydrofuran stirring for 1h at room temp. under N2; sepn. of ppt. on Kieselguhr, chromy. (silicagel(free of oxygen)) by Et2O, pentane and toluene/pentane(1/2);
参考文献
Angewandte Chemie, , vol. 101, p. 1525 - 1527
反应条件
in benzene warmed in sealed tube at 200-220°C for 3 h; evapd. in vac. dissolved in benzene/hexane (2:1), chromd. (Kieselgel), evapd.; elem. anal.;
参考文献
Chemische Berichte, , vol. 114, # 4 p. 1366 - 1381
