三羰基(η-环戊二烯基)合锰合成路线 （共 55 条）
反应条件
in further solvent(s) Kinetics; byproducts: Kr; 25 °C, in supercritical Kr; not isolated, detected by infrared spectroscopy;
参考文献
Journal of Physical Chemistry A, , vol. 104, # 18 p. 4300 - 4307
反应条件
in further solvent(s) Kinetics; byproducts: Xe; 25 °C, in supercritical Xe; not isolated, detected by infrared spectroscopy;
参考文献
Journal of Physical Chemistry A, , vol. 104, # 18 p. 4300 - 4307
反应条件
in benzene warmed in sealed tube at 160-180°C for 3 h; evapd. in vac. dissolved in benzene/hexane (2:1), chromd. (Kieselgel), evapd.; elem. anal.;
参考文献
Chemische Berichte, , vol. 114, # 4 p. 1366 - 1381
反应条件
in n-heptane under Ar; reflux, 1 h; filtration, chromy. (Al2O3, hexane-benzene), recrystn. (hexane);
参考文献
Russian Chemical Bulletin, , vol. 49, # 3 p. 526 - 532
反应条件
in tetrahydrofuran N2-atmosphere; stirring (room temp., 40 min), Mn-compd. addn., stirring (-90 to -70°C, 3 h); evapn. (vac., -50 to -40°C), chromy. (alumina, -25°C, petroleum ether, petroleum ether / CH2Cl2 = 20 : 1, petroleum ether / CH2Cl2/ Et2O = 10 : 1 : 1), evapn. (vac.), recrystn. (petroleum ether / CH2Cl 2, -80°C); elem. anal.;
参考文献
Organometallics, , vol. 17, # 4 p. 600 - 606
反应条件
in tetrahydrofuran under N2, addn. of C3O2 to the Mn complex in THF; evapn. to dryness (reduced pressure), sublimation (in vacuo at room temp.);
参考文献
Gazzetta Chimica Italiana, , vol. 115, # 10 p. 561 - 564
反应条件
in benzene-d6 byproducts: ((CH3)3C6H2)2C2N2H2PBr; dissolution of Mes2C2N2H2PC5H5 and Mn(CO)5Br in C6D6 under Ar; not isolated, NMR anal.;
参考文献
Dalton Transactions, , # 19 p. 1891 - 1897
反应条件
in solid byproducts: methane, acetone; thermolysis of Mn-complex in solid state at -30°C; monitoring by mass spectroscopy, chromy. of residue with toluene and THF (SiO2, -50°C);
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 38, # 11 p. 1497 - 1500
反应条件
in further solvent(s) Kinetics; byproducts: propane; keeping soln. of manganese compd. in liquid propane in presence of CO at293-318 K; IR monitoring;
参考文献
Journal of the American Chemical Society, , vol. 133, # 7 p. 2303 - 2310
反应条件
in toluene byproducts: acetone; addn. of PMe3 to Mn-complex in toluene at -78°C, warming from -78°C to 0°C, colour changes from light brown to yellow; evapn. of acetone (-60°C, vacuo), fractionated condensation, dissolution of residue in toluene, chromy. (SiO2, toluene, -60°C), elution of C5H5Mn(CO)3 with toluene, elution (Et2O) yields orangeyellow band, evapn., cooling (-20°C);
参考文献
Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 38, # 11 p. 1497 - 1500
