三羰基(η-环戊二烯基)合锰合成路线 （共 55 条）
反应条件
in deuterated toluene addn. of Pd2-complex to suspension of Mn-complex in toluene at -78°C; vigorous stirring;; centrifugation; detn. of react. by 1H-NMR;;
参考文献
Chemische Berichte, , vol. 119, # 9 p. 2777 - 2795
反应条件
in diethyl ether protective gas: Ar, abs. solvents; stirring (-20°C/3 h) of soln.;; filtration; evapn.; extraction (pentane); evapn.; drying (orange-brown oil/vac.); identified by IR-, 1H-NMR-spectroscopy;;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, p. 2421 - 2424
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 2606 - 2609
参考文献
Inorganic and Nuclear Chemistry Letters, , vol. 7, p. 587 - 590
反应条件
decompn. at 430°C; product: powder;
参考文献
Zhurnal Neorganicheskoi Khimii, , vol. 12, p. 592 - 593
Zhurnal Neorganicheskoi Khimii, , vol. 12, p. 1118 - 1120
C.A., , vol. 67, p. 47598
Mn: MVol.B, 2.5.2, page 33 - 35
反应条件
in hexane; water byproducts: cyclopentadiene; Irradiation (UV/VIS); Mn complex in hexane-H2O subjected to broad-band irradiation (300-800 nm) over 6 h; monitored by IR, (1)H NMR and mass spectra;
参考文献
Organometallics, , vol. 30, # 8 p. 2154 - 2159
