(1,5-环辛二烯)二氯化铂(II)合成路线 （共 69 条）
反应条件
in dimethylsulfoxide-d6 (N2, Schlenk technique); reaction of platinum compd. and 1 equiv. of phosphine deriv. in DMSO-d6; NMR;
参考文献
Dalton Transactions, , vol. 40, # 11 p. 2588 - 2600
反应条件
in dimethylsulfoxide-d6 (N2, Schlenk technique); reaction of platinum compd. and 1 equiv. of phosphine deriv. in presence of 6 equiv. of tetrabutylammonium chloride in DMSO-d6; NMR;
参考文献
Dalton Transactions, , vol. 40, # 11 p. 2588 - 2600
反应条件
in benzene (N2), soln. of Pt complex in benzene treated with 2 equiv. of phosphane,stirred at room temp. for 1 h; filtered, washed (benzene);
参考文献
Kajiyama, Kazumasa; Sato, Issei; Yamashita, Satoru; Miyamoto, Takeshi K.
European Journal of Inorganic Chemistry, 2009 , # 36 p. 5516 - 5521
反应条件
in dichloromethane stirring of equimolar amts. (room temp., 2 h); filtration, solvent removal (reduced pressure), addn. of CHCl3, filtration, addn. of Et2O, cooling;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 357 - 369
反应条件
KBr in dichloromethane byproducts: KCl; stirred for 48 h; filtration (removal of KCl);
参考文献
Kelly, Paul F.; Slawin, Alexandra M. Z.; Williams, David J.; Woollins, J. Derek
Polyhedron, 1988 , vol. 7, p. 1925 - 1930
反应条件
iodine in acetone slight excess of I2; solvent removal (vac.), washing (CCl4);
参考文献
Al-Najjar, Ibrahim M.
Inorganica Chimica Acta, 1987 , vol. 128, p. 93 - 104
参考文献
Jones, Nathan D.; MacFarlane, Kenneth S.; Smith, Martin B.; Schutte, Richard P.; Rettig, Steven J.; James, Brian R.
Inorganic Chemistry, 1999 , vol. 38, # 18 p. 3956 - 3966
反应条件
in toluene refluxing a mixt. of Rh-complex and Pt-compd. in toluene for 2 h (under N2, Schlenk technique);; pumping off, extn. (CH2Cl2), filtn. yields Pt-compd., evapn. of extract, chromy., elution (CH2Cl2/hexane) yields Rh-complex, elution (CH2Cl2), evapn., slow addn. of Et2O, cooling (-15°C), filtn., washing (Et2O), drying in vac., elem. anal.;;
参考文献
Ciriano, Miguel A.; Perez-Torrente, Jesus J.; Lahoz, Fernando J.; Oro, Luis A.
Inorganic Chemistry, 1992 , vol. 31, p. 969 - 974
反应条件
in dichloromethane 0.166667 h;
参考文献
US2005/107337 A1, ;
Page/Page column 3 ;
反应条件
triphenylphosphine in dichloromethane slow diffusion of diethyl ether in the CH2Cl2 soln., filtered off, washed with diethyl ether, dried (vac., 70°C);
参考文献
Inorganica Chimica Acta, , vol. 154, p. 89 - 94
