(1,5-环辛二烯)二氯化铂(II)合成路线 （共 69 条）
反应条件
in ethanol byproducts: COD; 10 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; recrystn. (benzene/ethanol);
参考文献
Goel, Anil B.; Goel, Sarla
Inorganica Chimica Acta, 1982 , vol. 65, p. L77 - L78
反应条件
in ethanol byproducts: COD; 1 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; evapn., extn. (benzene), recrystn. (benzene/hexane);
参考文献
Goel, Anil B.; Goel, Sarla
Inorganica Chimica Acta, 1982 , vol. 65, p. L77 - L78
反应条件
in ethanol byproducts: COD; 1 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; evapn., extn. (benzene), recrystn. (benzene/hexane);
参考文献
Goel, Anil B.; Goel, Sarla
Inorganica Chimica Acta, 1982 , vol. 65, p. L77 - L78
反应条件
in ethanol byproducts: COD; 10 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; recrystn. (benzene/ethanol);
参考文献
Goel, Anil B.; Goel, Sarla
Inorganica Chimica Acta, 1982 , vol. 65, p. L77 - L78
反应条件
in ethanol byproducts: COD; 10 equiv. of NaBH4, 2 equiv. of phosphine per complex, room temp., few min, gas evolution; recrystn. (benzene/ethanol);
参考文献
Goel, Anil B.; Goel, Sarla
Inorganica Chimica Acta, 1982 , vol. 65, p. L77 - L78
参考文献
Steenwinkel, Pablo; Jastrzebski, Johann T. B. H.; Deelman, Berth-Jan; Grove, David M.; Kooijman, Huub; Veldman, Nora; Smeets, Wilberth J. J.; Spek, Anthony L.; Van Koten, Gerard
Organometallics, 1997 , vol. 16, # 25 p. 5486 - 5498
反应条件
in tetrahydrofuran
byproducts: cycloocta-1,5-diene; stirring (room temp., 12 h); filtering, concg., pptn. on pentane addn. (-30°C), drying (vac.);elem. anal.;
参考文献
Van Der Boom, Milko E.; Kraatz, Heinz-Bernhard; Hassner, Lawrence; Ben-David, Yehoshoa; Milstein, David
Organometallics, 1999 , vol. 18, # 19 p. 3873 - 3884
反应条件
NaB(C2H5)3H in tetrahydrofuran
byproducts: NaCl, B(C2H5)3, H2; 60°C, 2 h; Washing with H2O to separate alkali halogenide from metal powder.;
参考文献
Boennemann, Helmut; Brijoux, Werner; Joussen, Thomas
Angewandte Chemie, 1990 , vol. 102, p. 324 - 326
反应条件
in chloroform-d1
byproducts: ethane; in NMR tube; 60°C for a few h; filtered; evapn. to dryness; detn. by NMR and MS;
参考文献
Molter, Anja; Mohr, Fabian
Zeitschrift fur Anorganische und Allgemeine Chemie, 2009 , vol. 635, # 1 p. 134 - 138
