3-甲基-5-(2,6,6-三甲基-1-环己烯-1-基)-2,4-戊二烯醛合成路线 （共 8 条）
反应条件
manganese(IV) oxide in hexane
参考文献
BEIERSDORF AF,
Patent: US2007/189984 A1, 2007 ;
Location in patent: Page/Page column 12-13 ;
反应条件
hydrogen bromide in water; acetone 0.666667 h; Heating;
参考文献
Launay, Valerie; Beaudet, Isabelle; Quintard, Jean-Paul
Bulletin de la Societe Chimique de France, 1997 , vol. 134, # 10,11 p. 937 - 946
反应条件
1: nBuLi / diethyl ether; hexane / 1 h / -70 - -60 °C 2: 73 percent / 2.) NH4Cl, H2O / diethyl ether / 1 h / 0 °C 3: 90 percent / hydrobromic acid / acetone; H2O / 0.67 h / Heating View Scheme
参考文献
Beaudet, Isabelle; Launay, Valerie; Parrain, Jean-Luc; Quintard, Jean-Paul
Tetrahedron Letters, 1995 , vol. 36, # 3 p. 389 - 392
反应条件
1: 73 percent / 2.) NH4Cl, H2O / diethyl ether / 1 h / 0 °C 2: 90 percent / hydrobromic acid / acetone; H2O / 0.67 h / Heating View Scheme
参考文献
Launay, Valerie; Beaudet, Isabelle; Quintard, Jean-Paul
Bulletin de la Societe Chimique de France, 1997 , vol. 134, # 10,11 p. 937 - 946
反应条件
water; hydrogen bromide Multistep reaction;
参考文献
Beaudet, Isabelle; Launay, Valerie; Parrain, Jean-Luc; Quintard, Jean-Paul
Tetrahedron Letters, 1995 , vol. 36, # 3 p. 389 - 392
反应条件
tert.-butyl lithium 1) ether, -70 deg C, 90 min, 2a) ether, -70 deg C, 1 h, 2b) -30 deg C, 1.5 h; Yield given. Multistep reaction;
参考文献
Duhamel, Lucette; Ancel, Jean-Erick
Tetrahedron, 1992 , vol. 48, # 42 p. 9237 - 9250
反应条件
tert.-butyl lithium 1) ether, -70 deg C, 90 min, 2a) ether, -70 deg C, 1 h, 2b) -30 deg C, 1.5 h; Yield given. Multistep reaction;
参考文献
Duhamel, Lucette; Ancel, Jean-Erick
Tetrahedron, 1992 , vol. 48, # 42 p. 9237 - 9250
反应条件
tert.-butyl lithium 1) ether, -70 deg C, 90 min, 2a) ether, -70 deg C, 1 h, 2b) -30 deg C, 1.5 h; Yield given. Multistep reaction;
参考文献
Duhamel, Lucette; Ancel, Jean-Erick
Tetrahedron, 1992 , vol. 48, # 42 p. 9237 - 9250
