(1,5-环辛二烯)氯铑(I)二聚体合成路线 （共 52 条）
反应条件
in acetone equivalent amount of org. compd. added to soln. of Rh complex in acetone;
参考文献
Leipoldt, J. G.; Grobler, E. C.
Inorganica Chimica Acta, 1983 , vol. 72, p. 17 - 20
反应条件
in ethanol refluxing;
参考文献
Schrock, R. R.; Osborn, J. A.
Journal of the American Chemical Society, 1971 , vol. 93, p. 2397 - 2407
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Gmelin Handbook: Rh: SVol.B3, 4.23.1, page 122 - 122
反应条件
triphenylphosphine in benzene (N2); Rh complex and phosphinederiv. (1/1 mol) was reacted in C6H6 (or C6D6); not isolated, detected by (1)H- and (31)P-NMR;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8) addn. of 3 equiv. of PPh3 to soln. of Rh-complex (25°C, NMR tube), (31)P-NMR monitoring at -40°C; not isolated;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in ethanol in hot ethanol;
参考文献
Nappier et al.
Journal of the American Chemical Society, 1973 , vol. 95, p. 4194,4195, 4204
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Nappier, T. E.; Meek, D. W.
Journal of the American Chemical Society, 1972 , vol. 94, p. 306 - 307
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Gmelin Handbook: Rh: SVol.B3, 4.26.3.1, page 188 - 191
反应条件
triphenylphosphine in ethanol 10-fold excess PPh3; refluxing; recrystn. from C6H6/C6H14;;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8) addn. of 3 equiv. of PPh3 to soln. of Rh-complex (25°C, NMR tube), (31)P-NMR monitoring at -40°C; not isolated;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
参考文献
Gmelin Handbook: Rh: SVol.B3, 4.24.3.1, page 131 - 132
反应条件
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8)
addn. of 3 equiv. of PPh3 and catecholborane to soln. of Rh-complex (25°C, (11)B-NMR monitoring); not isolated;
参考文献
Burgess, Kevin; Van Der Donk, Wilfred A.; Westcott, Stephen A.; Marder, Todd B.; Baker, R. Thomas; Calabrese, Joseph C.
Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9350 - 9359
反应条件
in dichloromethane-d2
under N2, molar ratio ligand : Rh-compd. = 1:0.5, room temp.; detn. by (1)H-NMR;
参考文献
Crociani, Bruno; Bianca, Francesca di; Paci, Maurizio; Boschi, Tristano
Inorganica Chimica Acta, 1988 , vol. 145, p. 253 - 266
